DICP OpenIR
Effect of low-temperature crystallization on physico-chemical properties of B-ZSM-5 and Ti-ZSM-5
Liu, M; Guo, XW; Gao, J; Wang, XS; Liu, XM; Han, XW; Bao, XH
KeywordBoron Titanium Zsm-5 Zeolite Gas-solid Method Phenol Hydroxylation
Source PublicationCHINESE JOURNAL OF CATALYSIS
2005-08-01
Volume26Issue:8Pages:660-664
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
AbstractThe Ti-ZSM-5 zeolite samples were successfully synthesized via gas-solid method with B-ZSM-5 zeolite prepared by modified hydrothermal synthesis as precursor. The samples were characterized by XRD, FT-IR, UV-Vis, XRF, SEM, ICP-AES and MAS NMR, and their catalytic performance for hydroxylation of phenol was investigated. The results showed that the crystallization at lower temperature during the synthesis of BZSM-5 was advantageous to get smaller crystal size and the Ti-ZSM-5 samples prepared by using B-ZSM-5 with smaller crystal size as precursor showed better performance for hydroxylation of phenol. Under the reaction conditions of n (PhOH) In (H2O2) = 3, n (Me2CO) In (PhOH) = 2.7, m (cat) /m (PhOH) = 5 %, T = 353 K and t = 6 h, the phenol conversion was over 20 %.
Language英语
WOS IDWOS:000231844100010
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139900
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, M,Guo, XW,Gao, J,et al. Effect of low-temperature crystallization on physico-chemical properties of B-ZSM-5 and Ti-ZSM-5[J]. CHINESE JOURNAL OF CATALYSIS,2005,26(8):660-664.
APA Liu, M.,Guo, XW.,Gao, J.,Wang, XS.,Liu, XM.,...&Bao, XH.(2005).Effect of low-temperature crystallization on physico-chemical properties of B-ZSM-5 and Ti-ZSM-5.CHINESE JOURNAL OF CATALYSIS,26(8),660-664.
MLA Liu, M,et al."Effect of low-temperature crystallization on physico-chemical properties of B-ZSM-5 and Ti-ZSM-5".CHINESE JOURNAL OF CATALYSIS 26.8(2005):660-664.
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