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Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor
Cai, R; Song, SQ; Ji, BF; Yang, WS; Sun, GQ; Xin, Q
关键词Phenol Oxidation Membrane Reactor Pemfc Electrochemical
刊名CATALYSIS TODAY
2005-06-30
DOI10.1016/j.cattod.2005.03.052
104期:2-4页:200-204
收录类别ISTP ; SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]FUEL-CELL SYSTEM ; OXYGEN REDUCTION ; OXIDATION ; BENZENE ; PERFORMANCE ; ELECTRODE
英文摘要In the present work, direct hydroxylation of benzene to phenol by using in situ generated H2O2 with electricity cogeneration was carried out in a proton exchange membrane fuel cell (PEMFC) reactor. Phenol was produced only when there was current through the external circuit. No other organic products were detected during this electrochemical process. A rotating ring-disc electrode (RRDE) technique was used to quantitatively detect the intermediate H2O2 in an acid electrolyte solution at different potentials and temperatures. The RRDE studies showed that the in situ generated H2O2 may play a crucial role during the formation of phenol. The formation rate of phenol could be controlled by adjusting the current or cell potential. (c) 2005 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000230204100014
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139928
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China
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Cai, R,Song, SQ,Ji, BF,et al. Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor[J]. CATALYSIS TODAY,2005,104(2-4):200-204.
APA Cai, R,Song, SQ,Ji, BF,Yang, WS,Sun, GQ,&Xin, Q.(2005).Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor.CATALYSIS TODAY,104(2-4),200-204.
MLA Cai, R,et al."Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor".CATALYSIS TODAY 104.2-4(2005):200-204.
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