中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand
作者: Mao, JC;  Wan, BS;  Wu, F;  Wang, RL;  Lu, SW
关键词: reversal of stereochemistry ;  enantioselective alkynylzinc addition ;  L-prolinol-backbone ;  propargylic alcohol ;  aldehyde
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 2005-05-03
DOI: 10.1016/j.molcata.2005.01.024
卷: 232, 期:1-2, 页:9-12
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Chiral ligands 1-2 with L-prolinol backbone have been applied to the enantioselective phenylacetylene addition to aldehydes, providing chiral propargylic alcohols in high yields and moderate enantioselectivities. Only the ligand 1 in combination with Ti((OPr)-Pr-i)(4) afforded the products with opposite absolute configuration in significant enantiomeric excesses and high yields. The ratio of Ti((OPr)-Pr-i)(4) to the ligand had great influence on the enantiomeric excess of the product. (c) 2005 Elsevier B.V. All fights reserved.
关键词[WOS]: ASYMMETRIC ADDITION ;  AROMATIC-ALDEHYDES ;  DIETHYLZINC ;  ALCOHOLS ;  ALKYNYLATION ;  ALKYNYLZINC ;  CATALYSTS ;  TITANIUM ;  COMPLEX ;  KETONES
语种: 英语
WOS记录号: WOS:000228203100002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139929
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China

Recommended Citation:
Mao, JC,Wan, BS,Wu, F,et al. Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2005,232(1-2):9-12.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Mao, JC]'s Articles
 [Wan, BS]'s Articles
 [Wu, F]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Mao, JC]‘s Articles
 [Wan, BS]‘s Articles
 [Wu, F]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace