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Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand
Mao, JC; Wan, BS; Wu, F; Wang, RL; Lu, SW
关键词Reversal Of Stereochemistry Enantioselective Alkynylzinc Addition L-prolinol-backbone Propargylic Alcohol Aldehyde
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2005-05-03
DOI10.1016/j.molcata.2005.01.024
232期:1-2页:9-12
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC ADDITION ; AROMATIC-ALDEHYDES ; DIETHYLZINC ; ALCOHOLS ; ALKYNYLATION ; ALKYNYLZINC ; CATALYSTS ; TITANIUM ; COMPLEX ; KETONES
英文摘要Chiral ligands 1-2 with L-prolinol backbone have been applied to the enantioselective phenylacetylene addition to aldehydes, providing chiral propargylic alcohols in high yields and moderate enantioselectivities. Only the ligand 1 in combination with Ti((OPr)-Pr-i)(4) afforded the products with opposite absolute configuration in significant enantiomeric excesses and high yields. The ratio of Ti((OPr)-Pr-i)(4) to the ligand had great influence on the enantiomeric excess of the product. (c) 2005 Elsevier B.V. All fights reserved.
语种英语
WOS记录号WOS:000228203100002
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被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139929
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
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GB/T 7714
Mao, JC,Wan, BS,Wu, F,et al. Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2005,232(1-2):9-12.
APA Mao, JC,Wan, BS,Wu, F,Wang, RL,&Lu, SW.(2005).Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,232(1-2),9-12.
MLA Mao, JC,et al."Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 232.1-2(2005):9-12.
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