中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)
作者: Yang, Jia-Zhen;  Zhang, Zhi-Heng;  Fang, Da-Wei;  Li, Ji-Guang;  Guan, Wei;  Tong, Jian
关键词: ionic liquid ;  isoperibol calorimeter ;  solution enthalpy ;  hydration heat ;  EMIBF4
刊名: FLUID PHASE EQUILIBRIA
发表日期: 2006-09-15
DOI: 10.1016/j.fluid.2006.06.016
卷: 247, 期:1-2, 页:80-83
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Thermodynamics ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Thermodynamics ;  Chemistry ;  Engineering
英文摘要: The molar solution enthalpies of ionic liquids (IL) EMIBF4 (1-methyl-3-ethylimidazolium tetrafluoroborate), EMIC (1-methyl-3-ethylimidazolium chloride) and ionic solid NaBF4 at various molalities were determined by the solution-reaction isoperibol calorimeter in water at 298.15 K. In terms of a Debye-Huckel limiting term, the molar solution enthalpies of EMIBF4, EMIC and NaBF4 at infinite dilution, A, H, were obtained. Then the values of apparent relative molar enthalpy were calculated. Hydration heat of both cation EMI+ and anion BF4- was discussed. In terms of values of Delta H-s(m)degrees, the reaction heat of NaBF4 + EMIC ->. EMIBF4 + NaCl was estimated. (c) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: THERMODYNAMIC PROPERTIES ;  AQUEOUS-SOLUTION ;  AMINO-ACIDS ;  WATER ;  CHLORIDE ;  CALORIMETER ;  DENSITY ;  LATTICE
语种: 英语
WOS记录号: WOS:000240563000010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140002
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Liaoning Univ, Dept Chem, Shenyang 110036, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China

Recommended Citation:
Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,et al. Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)[J]. FLUID PHASE EQUILIBRIA,2006,247(1-2):80-83.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Yang, Jia-Zhen]'s Articles
 [Zhang, Zhi-Heng]'s Articles
 [Fang, Da-Wei]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Yang, Jia-Zhen]‘s Articles
 [Zhang, Zhi-Heng]‘s Articles
 [Fang, Da-Wei]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace