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Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)
Yang, Jia-Zhen; Zhang, Zhi-Heng; Fang, Da-Wei; Li, Ji-Guang; Guan, Wei; Tong, Jian
关键词Ionic Liquid Isoperibol Calorimeter Solution Enthalpy Hydration Heat Emibf4
刊名FLUID PHASE EQUILIBRIA
2006-09-15
DOI10.1016/j.fluid.2006.06.016
247期:1-2页:80-83
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Thermodynamics ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Thermodynamics ; Chemistry ; Engineering
关键词[WOS]THERMODYNAMIC PROPERTIES ; AQUEOUS-SOLUTION ; AMINO-ACIDS ; WATER ; CHLORIDE ; CALORIMETER ; DENSITY ; LATTICE
英文摘要The molar solution enthalpies of ionic liquids (IL) EMIBF4 (1-methyl-3-ethylimidazolium tetrafluoroborate), EMIC (1-methyl-3-ethylimidazolium chloride) and ionic solid NaBF4 at various molalities were determined by the solution-reaction isoperibol calorimeter in water at 298.15 K. In terms of a Debye-Huckel limiting term, the molar solution enthalpies of EMIBF4, EMIC and NaBF4 at infinite dilution, A, H, were obtained. Then the values of apparent relative molar enthalpy were calculated. Hydration heat of both cation EMI+ and anion BF4- was discussed. In terms of values of Delta H-s(m)degrees, the reaction heat of NaBF4 + EMIC ->. EMIBF4 + NaCl was estimated. (c) 2006 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000240563000010
引用统计
被引频次:33[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140002
专题中国科学院大连化学物理研究所
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
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GB/T 7714
Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,et al. Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)[J]. FLUID PHASE EQUILIBRIA,2006,247(1-2):80-83.
APA Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,Li, Ji-Guang,Guan, Wei,&Tong, Jian.(2006).Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4).FLUID PHASE EQUILIBRIA,247(1-2),80-83.
MLA Yang, Jia-Zhen,et al."Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)".FLUID PHASE EQUILIBRIA 247.1-2(2006):80-83.
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