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题名: Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation
作者: Ren, Zefeng;  Che, Li;  Qiu, Minghui;  Wang, Xingan;  Dai, Dongxu;  Harich, Steven A.;  Wang, Xiuyan;  Yang, Xueming;  Xu, Chuanxiu;  Xie, Daiqian;  Sun, Zhigang;  Zhang, Dong H.
刊名: JOURNAL OF CHEMICAL PHYSICS
发表日期: 2006-10-21
DOI: 10.1063/1.2358680
卷: 125, 期:15
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: Full quantum state resolved scattering of the F atom reaction with H-2(j=0) and H-2(j=1) was investigated at the collision energies of 0.19 and 0.56 kcal/mol. Dramatic difference between the dynamics for the F+H-2(j=0,1) reactions at both collision energies have been observed. Forward scattering HF(v(')=2) products have been observed unambiguously for the F+H-2(j=1) reaction at low collision energies, which was attributed to the Feshbach resonances. This study provides a unique case of reaction resonances involving a rotationally excited reagent. (c) 2006 American Institute of Physics.
关键词[WOS]: POTENTIAL-ENERGY SURFACE ;  DIFFERENTIAL CROSS-SECTIONS ;  TRANSITION-STATE PATHWAYS ;  CHEMICAL-REACTION ;  F+H-2 REACTION ;  SCATTERING RESONANCES ;  REACTIVE SCATTERING ;  MOLECULAR-BEAM ;  F&H2 REACTION
语种: 英语
WOS记录号: WOS:000241405300002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140027
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
2.Nanjing Univ, Dept Chem, Inst Theoret & Computat Chem, Nanjing 210093, Jiangsu, Peoples R China
3.Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
4.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Theoret & Computat Chem, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Ren, Zefeng,Che, Li,Qiu, Minghui,et al. Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation[J]. JOURNAL OF CHEMICAL PHYSICS,2006,125(15).
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