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Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation
Ren, Zefeng; Che, Li; Qiu, Minghui; Wang, Xingan; Dai, Dongxu; Harich, Steven A.; Wang, Xiuyan; Yang, Xueming; Xu, Chuanxiu; Xie, Daiqian; Sun, Zhigang; Zhang, Dong H.
Source PublicationJOURNAL OF CHEMICAL PHYSICS
2006-10-21
DOI10.1063/1.2358680
Volume125Issue:15
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordPOTENTIAL-ENERGY SURFACE ; DIFFERENTIAL CROSS-SECTIONS ; TRANSITION-STATE PATHWAYS ; CHEMICAL-REACTION ; F+H-2 REACTION ; SCATTERING RESONANCES ; REACTIVE SCATTERING ; MOLECULAR-BEAM ; F&H2 REACTION
AbstractFull quantum state resolved scattering of the F atom reaction with H-2(j=0) and H-2(j=1) was investigated at the collision energies of 0.19 and 0.56 kcal/mol. Dramatic difference between the dynamics for the F+H-2(j=0,1) reactions at both collision energies have been observed. Forward scattering HF(v(')=2) products have been observed unambiguously for the F+H-2(j=1) reaction at low collision energies, which was attributed to the Feshbach resonances. This study provides a unique case of reaction resonances involving a rotationally excited reagent. (c) 2006 American Institute of Physics.
Language英语
WOS IDWOS:000241405300002
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140027
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
2.Nanjing Univ, Dept Chem, Inst Theoret & Computat Chem, Nanjing 210093, Jiangsu, Peoples R China
3.Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
4.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Theoret & Computat Chem, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Ren, Zefeng,Che, Li,Qiu, Minghui,et al. Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation[J]. JOURNAL OF CHEMICAL PHYSICS,2006,125(15).
APA Ren, Zefeng.,Che, Li.,Qiu, Minghui.,Wang, Xingan.,Dai, Dongxu.,...&Zhang, Dong H..(2006).Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation.JOURNAL OF CHEMICAL PHYSICS,125(15).
MLA Ren, Zefeng,et al."Probing Feshbach resonances in F+H-2(j=1)-> HF+H: Dynamical effect of single quantum H-2-rotation".JOURNAL OF CHEMICAL PHYSICS 125.15(2006).
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