DICP OpenIR
Reactions of platinum cluster ions with benzene
Liu, HT; Sun, ST; Xing, XP; Tang, ZC
刊名RAPID COMMUNICATIONS IN MASS SPECTROMETRY
2006
DOI10.1002/rcm.2524
20期:12页:1899-1904
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Analytical ; Spectroscopy
研究领域[WOS]Chemistry ; Spectroscopy
关键词[WOS]GAS-PHASE ; IONIZATION ENERGIES ; CATALYTIC-OXIDATION ; CYCLIC HYDROCARBONS ; BINDING-ENERGIES ; CARBON-MONOXIDE ; CHARGE-TRANSFER ; ANION CLUSTER ; COMPLEXES ; CHEMISORPTION
英文摘要In this work, the cation and anion products of the reactions between platinum clusters produced by laser ablation and the benzene molecules seeded in argon have been studied using a high-resolution reflectron time-of-flight mass spectrometer (RTOFMS). The dominant cation products are [C6nH6n-k](+) and [Pt-m(C6H6)(n)](+) complexes, while the dominant anion products are dehydrogenated species, [C6H5PtH](-), [PtC12Hk](-) and [PtmC6H4...(C6H6)(n)](-), etc. Some important intermediate structures ([PtC6H6](+), [Pt(C6H6)(2)](+), [Pt-2(C6H6)(3)](+), [C6H5PtH](-), [Pt2C6H4](-), [Pt3C6H4](-) and [Pt4C6H4](-)) have been analyzed using density functional theory (DFT) calculations. Different reaction mechanisms are proposed for platinum cluster cations and anions with benzene, respectively. Copyright (c) 2006 John Wiley & Sons, Ltd.
语种英语
WOS记录号WOS:000238333000014
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140039
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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Liu, HT,Sun, ST,Xing, XP,et al. Reactions of platinum cluster ions with benzene[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2006,20(12):1899-1904.
APA Liu, HT,Sun, ST,Xing, XP,&Tang, ZC.(2006).Reactions of platinum cluster ions with benzene.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,20(12),1899-1904.
MLA Liu, HT,et al."Reactions of platinum cluster ions with benzene".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 20.12(2006):1899-1904.
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