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Influence of partial replacement of Cu by Fe on the CWO of phenol in the CU0.5-xFexZn0.5Al2O4 spinel catalysts
Xu, Aihua; Yang, Min; Du, Hongzhang; Sun, Chenglin
关键词Catalytic Wet Oxidation Phenol Leaching Carbonaceous Deposits Spinel Cation Distribution
刊名CATALYSIS COMMUNICATIONS
2006-08-01
DOI10.1016/j.catcom.2005.11.020
7期:8页:513-517
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]WET AIR OXIDATION ; AQUEOUS-SOLUTIONS ; CRYSTAL-CHEMISTRY ; PRECURSORS ; STABILITY
英文摘要The activity and stability of the Cu0.5-x FexZn0.5Al2O4 spinel type catalysts prepared by sol-gel method were studied in the catalytic wet oxidation of phenol. All catalysts showed high catalytic activity and leach-proof ability. The loss of activity for the catalysts (x <= 0.25) can be attributed to the elution of the active phase. The cation distribution of the spinel was calculated from XRD and it has been found that the amount of Cu-leached ions in CWO reaction decreases with the fraction of Cu ions occupied in the octahedral sites decreasing. (c) 2006 Published by Elsevier B.V.
语种英语
WOS记录号WOS:000238799500001
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140056
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
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GB/T 7714
Xu, Aihua,Yang, Min,Du, Hongzhang,et al. Influence of partial replacement of Cu by Fe on the CWO of phenol in the CU0.5-xFexZn0.5Al2O4 spinel catalysts[J]. CATALYSIS COMMUNICATIONS,2006,7(8):513-517.
APA Xu, Aihua,Yang, Min,Du, Hongzhang,&Sun, Chenglin.(2006).Influence of partial replacement of Cu by Fe on the CWO of phenol in the CU0.5-xFexZn0.5Al2O4 spinel catalysts.CATALYSIS COMMUNICATIONS,7(8),513-517.
MLA Xu, Aihua,et al."Influence of partial replacement of Cu by Fe on the CWO of phenol in the CU0.5-xFexZn0.5Al2O4 spinel catalysts".CATALYSIS COMMUNICATIONS 7.8(2006):513-517.
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