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题名: Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates
作者: Liu, Hui;  Zhou, Yong-Gui;  Yu, Zheng-Kun;  Xiao, Wen-Jing;  Liu, Sheng-Hua;  He, Hong-Wu
关键词: asymmetric catalysis ;  chirality ;  phosphonate ;  hydrogenation
刊名: TETRAHEDRON
发表日期: 2006-11-27
DOI: 10.1016/j.tet.2006.09.011
卷: 62, 期:48, 页:11207-11217
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Optically active alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates have been synthesized via catalytic asymmetric hydrogenation of the corresponding prochiral alpha,beta-unsaturated phosphonates using Rh(I)/(R,R)-Me-DuPhos as the catalyst in methanol at 18 degrees C. The asymmetric hydrogenation reaction exhibits excellent enantioselectivity with enantiomeric excesses from 91 to 96%. (c) 2006 Elsevier Ltd. All rights reserved.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  STATE ANALOG INHIBITORS ;  AMINO PHOSPHONATES ;  HYDROXY PHOSPHONATES ;  ACID-DERIVATIVES ;  HIV-PROTEASE ;  COMPLEXES ;  PHOSPHONOPEPTIDES ;  ENAMIDES ;  OXIDES
语种: 英语
WOS记录号: WOS:000241967600021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140066
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Liu, Hui,Zhou, Yong-Gui,Yu, Zheng-Kun,et al. Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates[J]. TETRAHEDRON,2006,62(48):11207-11217.
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