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Stereoselective hydroxycarbonylation of vinyl bromides to alpha,beta-unsaturated carboxylic acids in the ionic liquid [BMIM]PF6
Zhao, XD; Alper, H; Yu, ZK
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2006-05-12
DOI10.1021/jo052651p
Volume71Issue:10Pages:3988-3990
Indexed BySCI ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordTRANS-CINNAMIC ACIDS ; HECK REACTION ; COUPLING REACTIONS ; HIGHLY EFFICIENT ; ARYL HALIDES ; PALLADIUM ; CARBONYLATION ; CATALYST ; NANOPARTICLES ; DERIVATIVES
Abstract(E/Z)-Isomers containing vinyl bromides were stereoselectively carbonylated to the corresponding (E)-alpha,beta-ethylenic carboxylic acids in the ionic liquid [BMIM]PF6. Vinyl dibromides also underwent hydroxycarbonylation to give monoacids. The products are pure by proton NMR spectroscopic determination without purification by silica gel column chromatograghy or recrystallization.
Language英语
WOS IDWOS:000237417400046
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140102
Collection中国科学院大连化学物理研究所
Affiliation1.Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhao, XD,Alper, H,Yu, ZK. Stereoselective hydroxycarbonylation of vinyl bromides to alpha,beta-unsaturated carboxylic acids in the ionic liquid [BMIM]PF6[J]. JOURNAL OF ORGANIC CHEMISTRY,2006,71(10):3988-3990.
APA Zhao, XD,Alper, H,&Yu, ZK.(2006).Stereoselective hydroxycarbonylation of vinyl bromides to alpha,beta-unsaturated carboxylic acids in the ionic liquid [BMIM]PF6.JOURNAL OF ORGANIC CHEMISTRY,71(10),3988-3990.
MLA Zhao, XD,et al."Stereoselective hydroxycarbonylation of vinyl bromides to alpha,beta-unsaturated carboxylic acids in the ionic liquid [BMIM]PF6".JOURNAL OF ORGANIC CHEMISTRY 71.10(2006):3988-3990.
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