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Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde
Zhang, HD; Zhang, J; Sun, KQ; Feng, ZC; Ying, PL; Li, C
KeywordMethane Selective Oxidation Formaldehyde Antimony-vanadium Mixed Oxide Phase Transform
Source PublicationCATALYSIS LETTERS
2006
DOI10.1007/s10562-005-9196-1
Volume106Issue:1-2Pages:89-93
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordDIRECT CONVERSION ; OXYGEN ; CHALLENGE
AbstractSb-V-O/SiO2 catalysts were prepared and investigated in methane selective oxidation with O-2 as oxidant. Sb-V-O/SiO2 catalysts are active and selective in methane selective oxidation. The formaldehyde yield obtained on Sb-V-O/SiO2 catalysts is clearly higher than that for VOX/SiO2 and SbOX/SiO2 catalysts. A one-pass formaldehyde yield up to 3% was obtained on Sb-V-O/SiO2 catalysts at 650 degrees C. XRD and UV Raman studies showed that the phase of Sb-V mixed oxide on Sb-V-O/SiO2 catalysts transformed with decreasing Sb/V ratio from Sb2VO5 to SbVO4/VSb1-XO4-1.5X phase. The Sb-V mixed oxide in Sb2VO5 phase is more active and selective than that in SbVO4/VSb1-XO4-1.5X phase.
Language英语
WOS IDWOS:000234298700015
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140106
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, HD,Zhang, J,Sun, KQ,et al. Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde[J]. CATALYSIS LETTERS,2006,106(1-2):89-93.
APA Zhang, HD,Zhang, J,Sun, KQ,Feng, ZC,Ying, PL,&Li, C.(2006).Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde.CATALYSIS LETTERS,106(1-2),89-93.
MLA Zhang, HD,et al."Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde".CATALYSIS LETTERS 106.1-2(2006):89-93.
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