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EFFECT OF COLUMN TEMPERATURE ON RETENTION OF DIPEPTIDE ISOMERS IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
ZOU, HF; ZHANG, YK; HONG, MF; LU, PC
刊名JOURNAL OF LIQUID CHROMATOGRAPHY
1992
15期:13页:2289-2296
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences
类目[WOS]Biochemical Research Methods ; Chemistry, Analytical
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry
关键词[WOS]AROMATIC-HYDROCARBONS ; BEHAVIOR ; SEPARATIONS ; PARAMETER ; HPLC
英文摘要The effect of column temperature on the capacity factor and selectivity of dipeptide isomers was investigated. It has been observed that the variation in the logarithm of the capacity factor of dipeptide isomers is linearly dependent on the reciprocal of the absolute column temperature. The standard enthalpic change for dipeptide isomers is almost a constant, and the selectivity value is almost independent of the column temperature. It can be concluded that (1) the enthalpy change of dipeptide isomers in RP-HPLC is mainly determined by the molecular interaction in the mobile phase and (2) the difference of their standard entropy change play more important role in the selectivity value than that of standard enthalpy change does.
语种英语
WOS记录号WOS:A1992JK13200005
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被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140116
专题中国科学院大连化学物理研究所
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GB/T 7714
ZOU, HF,ZHANG, YK,HONG, MF,et al. EFFECT OF COLUMN TEMPERATURE ON RETENTION OF DIPEPTIDE ISOMERS IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY[J]. JOURNAL OF LIQUID CHROMATOGRAPHY,1992,15(13):2289-2296.
APA ZOU, HF,ZHANG, YK,HONG, MF,&LU, PC.(1992).EFFECT OF COLUMN TEMPERATURE ON RETENTION OF DIPEPTIDE ISOMERS IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY.JOURNAL OF LIQUID CHROMATOGRAPHY,15(13),2289-2296.
MLA ZOU, HF,et al."EFFECT OF COLUMN TEMPERATURE ON RETENTION OF DIPEPTIDE ISOMERS IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY".JOURNAL OF LIQUID CHROMATOGRAPHY 15.13(1992):2289-2296.
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