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题名: Molar heat capacities, thermodynamic properties, and thermal stability of the synthetic complex [Er(Pro)(2)(H2O)(5)]Cl-3
作者: Lv, Xue-Chuan;  Liu, Bei-Ping;  Tan, Zhi-Cheng;  Li, Yan-Sheng;  Zhang, Zhi-Heng;  Shi, Quan;  Sun, Li-Xian;  Tao-Zhang
刊名: JOURNAL OF CHEMICAL AND ENGINEERING DATA
发表日期: 2006-09-14
DOI: 10.1021/je0505220
卷: 51, 期:5, 页:1526-1529
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The molar heat capacity, C-p,C-m, of a complex of erbium chloride coordinated with L-proline, [Er(Pro)(2)(H2O)(5)]Cl-3, was measured from T) 80 K to T) 400 K with an automated adiabatic calorimeter. The temperature, the molar enthalpy, and the entropy of fusion and decomposition were calculated using equations and diagrammatic area integration. The thermodynamic functions [H-T-H-298.15] and [S-T-S-298.15] were derived from T = 80 K to T = 360 K with a temperature interval of 5 K. The thermal stability of the compound was investigated by differential scanning calorimetry and the thermogravimetric techniques.
关键词[WOS]: ADIABATIC CALORIMETER ;  CRYSTAL-STRUCTURE
语种: 英语
WOS记录号: WOS:000240496200007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140121
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
2.Hunan Univ Arts & Sci, Dept Chem, Changde 415000, Peoples R China
3.Dalian Jiaotong Univ, Coll Environm Sci & Engn, Dalian 116028, Peoples R China

Recommended Citation:
Lv, Xue-Chuan,Liu, Bei-Ping,Tan, Zhi-Cheng,et al. Molar heat capacities, thermodynamic properties, and thermal stability of the synthetic complex [Er(Pro)(2)(H2O)(5)]Cl-3[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2006,51(5):1526-1529.
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