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题名: Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst
作者: Qiu, Jieshan;  Zhang, Hongzhe;  Wang, Xiuna;  Han, Hongmei;  Liang, Changhai;  Li, Can
关键词: carbon nanotubes ;  hydrogenation of cinnamaldehyde ;  palladium and ruthenium
刊名: REACTION KINETICS AND CATALYSIS LETTERS
发表日期: 2006-08-01
DOI: 10.1007/s11144-006-0061-z
卷: 88, 期:2, 页:269-275
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Carbon nanotube supported Pd, Ru and Pd-Ru catalysts have been prepared and tested with the hydrogenation of cinnamaldehyde as a probe reaction. It has been found that the cinnamaldehyde conversion and the selectivity towards the hydrogenation of C=O bond over Pd-Ru/PCNT catalyst could reach 56.6% and 79.1%, respectively, at 120 degrees C and 5.0 MPa, which is better than Pd/PCNT and Ru/PCNT catalysts under the same reaction conditions. It is assumed that the better performance of Pd-Ru/PCNT catalyst for cinnamaldehyde hydrogenation may be due to the synergic effect of Pd and Ru metals or the promoting effect of Ru metal.
关键词[WOS]: ALPHA,BETA-UNSATURATED ALDEHYDES ;  PLATINUM
语种: 英语
WOS记录号: WOS:000239050100009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140156
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Sch Chem Engn, Ctr Nanomat & Sci,Carbon Res Lab, State Key Lab Fine Chem, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
3.Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany

Recommended Citation:
Qiu, Jieshan,Zhang, Hongzhe,Wang, Xiuna,et al. Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst[J]. REACTION KINETICS AND CATALYSIS LETTERS,2006,88(2):269-275.
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