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题名: Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by bifunctional tridentate bis(oxazoline)-Zn(II) complex
作者: Lu, SF;  Du, DM;  Xu, JX
刊名: ORGANIC LETTERS
发表日期: 2006-05-11
DOI: 10.1021/ol060586f
卷: 8, 期:10, 页:2115-2118
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A more practical and efficient catalytic asymmetric Friedel-Crafts alkylation of indoles with nitroalkenes using bifunctional tridentate bis(oxazoline)-Zn(OTf)(2) as catalyst has been developed. Various types of the nitroalkylated indoles were obtained in excellent yields (85-99%) and high enantioselectivities (up to 98% ee).
关键词[WOS]: BIS(OXAZOLINYL)PYRIDINE-SCANDIUM(III) TRIFLATE COMPLEXES ;  NH/PI INTERACTION ;  HENRY REACTION ;  BIS(THIAZOLINE) ;  LIGANDS
语种: 英语
WOS记录号: WOS:000237420200039
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140181
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem & Mol Engn, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

Recommended Citation:
Lu, SF,Du, DM,Xu, JX. Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by bifunctional tridentate bis(oxazoline)-Zn(II) complex[J]. ORGANIC LETTERS,2006,8(10):2115-2118.
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