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Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides
Fang, Tao; Xu, Jiaxi; Du, Da-Ming
KeywordAsymmetric Reduction Borane Ketone Beta-hydroxyamide C-3 Symmetry
Source PublicationSYNLETT
2006-06-11
DOI10.1055/s-2006-94159
Issue10Pages:1559-1563
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordMEDIATED ASYMMETRIC REDUCTION ; AROMATIC KETONES ; CHIRAL OXAZABOROLIDINES ; AMINO-ALCOHOLS ; REDUCING AGENT ; ALDEHYDES ; NABH4/ME3SICL ; RECOGNITION ; SULFONAMIDE
AbstractThe asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-symmetric tripodal tris(beta-hydroxyamide) ligands was investigated. The borane complex of chiral ligand 1,1',1"-(1,3,5-benzenetricarbonyl)-tris[(2S)-alpha,alpha-diphenl-2-pyrrolidinemethanol] (1h) was found to be an efficient catalyst in asymmetric borane reduction of prochiral ketones and excellent enantioselectivities were obtained with both electron-deficient and electron-rich prochiral ketones (up to 97% ee).
Language英语
WOS IDWOS:000238732100021
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140191
Collection中国科学院大连化学物理研究所
AffiliationPeking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Fang, Tao,Xu, Jiaxi,Du, Da-Ming. Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides[J]. SYNLETT,2006(10):1559-1563.
APA Fang, Tao,Xu, Jiaxi,&Du, Da-Ming.(2006).Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides.SYNLETT(10),1559-1563.
MLA Fang, Tao,et al."Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides".SYNLETT .10(2006):1559-1563.
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