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题名: Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides
作者: Fang, Tao;  Xu, Jiaxi;  Du, Da-Ming
关键词: asymmetric reduction ;  borane ;  ketone ;  beta-hydroxyamide ;  C-3 symmetry
刊名: SYNLETT
发表日期: 2006-06-11
DOI: 10.1055/s-2006-94159
期: 10, 页:1559-1563
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-symmetric tripodal tris(beta-hydroxyamide) ligands was investigated. The borane complex of chiral ligand 1,1',1"-(1,3,5-benzenetricarbonyl)-tris[(2S)-alpha,alpha-diphenl-2-pyrrolidinemethanol] (1h) was found to be an efficient catalyst in asymmetric borane reduction of prochiral ketones and excellent enantioselectivities were obtained with both electron-deficient and electron-rich prochiral ketones (up to 97% ee).
关键词[WOS]: MEDIATED ASYMMETRIC REDUCTION ;  AROMATIC KETONES ;  CHIRAL OXAZABOROLIDINES ;  AMINO-ALCOHOLS ;  REDUCING AGENT ;  ALDEHYDES ;  NABH4/ME3SICL ;  RECOGNITION ;  SULFONAMIDE
语种: 英语
WOS记录号: WOS:000238732100021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140191
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

Recommended Citation:
Fang, Tao,Xu, Jiaxi,Du, Da-Ming. Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides[J]. SYNLETT,2006(10):1559-1563.
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