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Catalytic activity of H beta zeolite for cyclohexyl hydroperoxide decomposition
Sun, ZQ; Xu, J; Du, ZT; Zhang, W
关键词h Beta Zeolite Cyclohexyl Hydroperoxide Decomposition Cyclohexanol Cyclohexanone
刊名CHINESE JOURNAL OF CATALYSIS
2006-04-01
27期:4页:299-300
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]AL-27 MAS ; DEALUMINATION ; NMR
英文摘要The transition metal free acidic zeolite H beta has been found to be very active for the decomposition of cyclohexyl hydroperoxide. A remarkable high TOF of 181.9 h(-1) was achieved with H beta, which is almost equal to the TOF over 5 % Ru/Al2O3. The total selectivity for the main products cyclohexanol and cyclohexanone reached 84.6 %. The reaction temperature greatly affected the decomposition rate and product selectivity.
语种英语
WOS记录号WOS:000237431800004
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140291
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
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Sun, ZQ,Xu, J,Du, ZT,et al. Catalytic activity of H beta zeolite for cyclohexyl hydroperoxide decomposition[J]. CHINESE JOURNAL OF CATALYSIS,2006,27(4):299-300.
APA Sun, ZQ,Xu, J,Du, ZT,&Zhang, W.(2006).Catalytic activity of H beta zeolite for cyclohexyl hydroperoxide decomposition.CHINESE JOURNAL OF CATALYSIS,27(4),299-300.
MLA Sun, ZQ,et al."Catalytic activity of H beta zeolite for cyclohexyl hydroperoxide decomposition".CHINESE JOURNAL OF CATALYSIS 27.4(2006):299-300.
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