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Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid
Liu Ying; Ding Guosheng; Xu Xiuming; Hao Weiqiang; Wei Guilin; Wang Junde
关键词Molecularly Imprinted Polymer Metal Coordination-chelation Interaction Chiral Separation Mandelic Acid
刊名CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2006-06-01
34期:6页:871-874
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical
研究领域[WOS]Chemistry
关键词[WOS]TEMPLATE-MEDIATED SYNTHESIS ; RECOGNITION
英文摘要Metal-complexing imprinted polymer for L-mandelic acid was prepared using Cu(II)-[N-(4-vinylbenzyl)] iminodiacetic acid as functional monomer, trimethylolpropane trimethacrylate as crosslinker and methanol as porogenic agent. Chiral separation ability of metal-complexing imprinted polymer to D,L-mandelic acid was investigated by high performance liquid chromatography. The mobile phase conditions (pH, methanol content, buffer concentration, etc.) could significantly influence the chiral separation ability of metal-complexing imprinted polymer. Highly chiral selective to the template molecule by metal-complexing imprinted polymer was achieved as pH 7-9 of the mobile phase; the chiral separation ability of metal-complexing imprinted polymer was increased with the increase of methanol content and buffer concentration. It is suggested the feasibility to prepare highly selective molecularly imprinted polymer in polar solvent.
语种英语
WOS记录号WOS:000240869900031
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140293
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
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GB/T 7714
Liu Ying,Ding Guosheng,Xu Xiuming,et al. Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2006,34(6):871-874.
APA Liu Ying,Ding Guosheng,Xu Xiuming,Hao Weiqiang,Wei Guilin,&Wang Junde.(2006).Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,34(6),871-874.
MLA Liu Ying,et al."Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 34.6(2006):871-874.
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