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题名: Quantitative interpretation of polarization SFG Vibrational Spectra of air/methanol interface
作者: Hui Wu;  Wen-kai Zhang;  Wei Gan;  Zhi-feng Cui;  Hong-fei Wang
关键词: Sum Frequency Generation ;  bond additivity model ;  Raman polarizability
刊名: CHINESE JOURNAL OF CHEMICAL PHYSICS
发表日期: 2006-06-27
DOI: 10.1360/cjcp2006.19(3).187.3
卷: 19, 期:3, 页:187-189
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: Even though in IR and Raman spectra of liquid methanol there is always an apparent feature for the asymmetric stretching mode of the CH3 group around 2970 cm(-1), this feature has not been observed in the Sum Frequency Generation Vibrational Spectroscopy (SFG-VS) in any polarizations from the air/methanol interface. Here we present a treatment based on a corrected bond additivity model to quantitatively interpret the SFG-VS of the air/methanol interface from the IR and Raman spectra of liquid methanol.
关键词[WOS]: SUM-FREQUENCY GENERATION ;  LIQUID-VAPOR INTERFACE ;  BOND MOMENTS ;  MOLECULAR-ORIENTATION ;  INFRARED INTENSITIES ;  SPECTROSCOPY ;  SURFACE ;  METHANOL ;  METHYL ;  WATER
语种: 英语
WOS记录号: WOS:000238867600001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140297
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Anhui Normal Univ, Dept Phys, Wuhu 241000, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Hui Wu,Wen-kai Zhang,Wei Gan,et al. Quantitative interpretation of polarization SFG Vibrational Spectra of air/methanol interface[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2006,19(3):187-189.
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