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题名: Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand
作者: Zhu, Di;  Wang, Rongliang;  Mao, Jincheng;  Xu, Lei;  Wu, Fan;  Wan, Boshun
关键词: Amination ;  copper ;  aryl halides ;  cross-coupling ;  rac-BINOL ;  ligand
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 2006-08-18
DOI: 10.1016/j.molcata.2006.05.005
卷: 256, 期:1-2, 页:256-260
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A highly efficient copper-catalyzed system using commercially available racemic 1,1'-binaphthyl-2,2'-diol (rac-BINOL) as the ligand was developed for amination of aryl halides and heteroaryl halides with alkyl amines and N-H heterocycles. Good to high yields were obtained for aryl bromides and heteroaryl chlorides. The commercially available rac-BINOL ligand with excellent stability and high efficiency for aryl bromides and heteroaryl chlorides ultimately make this protocol of potentially practical utility. (c) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: CROSS-COUPLING REACTIONS ;  BOND FORMATION ;  C-N ;  NITROGEN-HETEROCYCLES ;  BUCHWALDS PROTOCOL ;  GOLDBERG REACTIONS ;  ULLMANN REACTION ;  FACILE SYNTHESIS ;  ARYLATION ;  IODIDES
语种: 英语
WOS记录号: WOS:000240365800036
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140328
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Zhu, Di,Wang, Rongliang,Mao, Jincheng,et al. Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2006,256(1-2):256-260.
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