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Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand
Zhu, Di; Wang, Rongliang; Mao, Jincheng; Xu, Lei; Wu, Fan; Wan, Boshun
KeywordAmination Copper Aryl Halides Cross-coupling Rac-binol Ligand
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2006-08-18
DOI10.1016/j.molcata.2006.05.005
Volume256Issue:1-2Pages:256-260
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordCROSS-COUPLING REACTIONS ; BOND FORMATION ; C-N ; NITROGEN-HETEROCYCLES ; BUCHWALDS PROTOCOL ; GOLDBERG REACTIONS ; ULLMANN REACTION ; FACILE SYNTHESIS ; ARYLATION ; IODIDES
AbstractA highly efficient copper-catalyzed system using commercially available racemic 1,1'-binaphthyl-2,2'-diol (rac-BINOL) as the ligand was developed for amination of aryl halides and heteroaryl halides with alkyl amines and N-H heterocycles. Good to high yields were obtained for aryl bromides and heteroaryl chlorides. The commercially available rac-BINOL ligand with excellent stability and high efficiency for aryl bromides and heteroaryl chlorides ultimately make this protocol of potentially practical utility. (c) 2006 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000240365800036
Citation statistics
Cited Times:58[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140328
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Di,Wang, Rongliang,Mao, Jincheng,et al. Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2006,256(1-2):256-260.
APA Zhu, Di,Wang, Rongliang,Mao, Jincheng,Xu, Lei,Wu, Fan,&Wan, Boshun.(2006).Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,256(1-2),256-260.
MLA Zhu, Di,et al."Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 256.1-2(2006):256-260.
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