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Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts
Wang Hong; Liu Jian; Liu Peng; Yang Qihua; Xiao Jianliang; Li Can
关键词Supported Catalyst Bis(Oxazoline) Complex Diels-alder Reaction Activated Silica Sba-15
刊名CHINESE JOURNAL OF CATALYSIS
2006-11-01
27期:11页:946-948
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]MESOPOROUS ORGANOSILICAS ; HETEROGENEOUS CATALYSTS ; HOMOGENEOUS CATALYSTS ; ACID ; ENANTIOSELECTIVITY ; COMPLEXES ; CYCLOPROPANATION ; IMMOBILIZATION ; LIGANDS ; SILICA
英文摘要Periodic mesoporous ethane-silicas functionalized with sulfonic acid, cesium salts of 12-tungstophosphoric acid, activated silica, and SBA-15 have been used as solid supports for the immobilization of the bis(oxazoline) copper (II) catalyst via non-covalent interactions. These heterogeneous catalysts have been evaluated for the Diels-Alder reaction between 3-((E)-2-butenoyl)-1,3-oxazolin-2-one and cyclopentadiene. The performance of the catalyst relies on the nature of both the support and the anion on the surface of the support. The small number of the silanol groups on the support leads to poor enantloselectivity when SBA-15 is used.
语种英语
WOS记录号WOS:000242869300004
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140343
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
推荐引用方式
GB/T 7714
Wang Hong,Liu Jian,Liu Peng,et al. Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2006,27(11):946-948.
APA Wang Hong,Liu Jian,Liu Peng,Yang Qihua,Xiao Jianliang,&Li Can.(2006).Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts.CHINESE JOURNAL OF CATALYSIS,27(11),946-948.
MLA Wang Hong,et al."Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts".CHINESE JOURNAL OF CATALYSIS 27.11(2006):946-948.
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