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Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite
Shao, X; Luo, XC; Hu, XQ; Wu, K
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY B
2006-01-26
DOI10.1021/jp055910n
Volume110Issue:3Pages:1288-1293
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordSCANNING-TUNNELING-MICROSCOPY ; LIQUID-SOLID INTERFACE ; PHYSISORBED MONOLAYERS ; STM INVESTIGATIONS ; ACID-DERIVATIVES ; TRIMESIC ACID ; MOLECULES ; PHTHALOCYANINE ; METALLACYCLES ; ARCHITECTURES
Abstract3,8-Bis-hexadecyloxy-benzo[c]cinnoline (BBC16) self-assembled into two structures at highly oriented pyrolytic graphite (HOPG) surface: one was formed by molecules with a V-like configuration (C-2v symmetry) and the other by molecules with a Z-like configuration (C-s symmetry). The self-assembled structures could be tweaked by the solvents used. In the self-assembled monolayers (SAMs) on HOPG, the BBC16 molecule adopted the V-like configuration in polar solvents and the Z-like configuration in nonpolar solvents. Moreover, the solvent viscosity, solvent dissolvability of BBC16, and substrate temperature also played some roles in tuning the two-dimensional self-assembled structures.
Language英语
WOS IDWOS:000235046300031
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140354
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Inst Phys Chem, State Key Lab Struct Chem & Unstable & Stable Spe, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Shao, X,Luo, XC,Hu, XQ,et al. Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2006,110(3):1288-1293.
APA Shao, X,Luo, XC,Hu, XQ,&Wu, K.(2006).Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite.JOURNAL OF PHYSICAL CHEMISTRY B,110(3),1288-1293.
MLA Shao, X,et al."Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite".JOURNAL OF PHYSICAL CHEMISTRY B 110.3(2006):1288-1293.
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