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题名: Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite
作者: Shao, X;  Luo, XC;  Hu, XQ;  Wu, K
刊名: JOURNAL OF PHYSICAL CHEMISTRY B
发表日期: 2006-01-26
DOI: 10.1021/jp055910n
卷: 110, 期:3, 页:1288-1293
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: 3,8-Bis-hexadecyloxy-benzo[c]cinnoline (BBC16) self-assembled into two structures at highly oriented pyrolytic graphite (HOPG) surface: one was formed by molecules with a V-like configuration (C-2v symmetry) and the other by molecules with a Z-like configuration (C-s symmetry). The self-assembled structures could be tweaked by the solvents used. In the self-assembled monolayers (SAMs) on HOPG, the BBC16 molecule adopted the V-like configuration in polar solvents and the Z-like configuration in nonpolar solvents. Moreover, the solvent viscosity, solvent dissolvability of BBC16, and substrate temperature also played some roles in tuning the two-dimensional self-assembled structures.
关键词[WOS]: SCANNING-TUNNELING-MICROSCOPY ;  LIQUID-SOLID INTERFACE ;  PHYSISORBED MONOLAYERS ;  STM INVESTIGATIONS ;  ACID-DERIVATIVES ;  TRIMESIC ACID ;  MOLECULES ;  PHTHALOCYANINE ;  METALLACYCLES ;  ARCHITECTURES
语种: 英语
WOS记录号: WOS:000235046300031
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140354
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem & Mol Engn, Inst Phys Chem, State Key Lab Struct Chem & Unstable & Stable Spe, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Shao, X,Luo, XC,Hu, XQ,et al. Solvent effect on self-assembled structures of 3,8-bis-hexadecyloxy-benzo[c]cinnoline on highly oriented pyrolytic graphite[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2006,110(3):1288-1293.
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