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题名: A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol
作者: Gao, Xiaohan;  Xu, Jie
关键词: clay ;  benzene ;  phenol ;  vanadium
刊名: APPLIED CLAY SCIENCE
发表日期: 2006-06-01
DOI: 10.1016/j.clay.2005.12.002
卷: 33, 期:1, 页:1-6
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Physical ;  Materials Science, Multidisciplinary ;  Mineralogy
研究领域[WOS]: Chemistry ;  Materials Science ;  Mineralogy
英文摘要: The highly selective direct hydroxylation of benzene with hydrogen peroxide to phenol was observed on a clay-supported vanadium oxide catalyst. Under mild reaction conditions at 313 K, high selectivity to phenol of 94% was realized on the clay-supported vanadium oxide catalyst at 14% conversion of benzene, comparable with the well-known TS-1 catalyst. On the other hand, vanadium on other supports and other metals on the clay support gave inferior catalytic performances. V-O-Al and V-O-Si bridges in the catalyst may be responsible for the reaction. (c) 2005 Elsevier B.V. All rights reserved.
关键词[WOS]: HYDROGEN-PEROXIDE ;  IR-SPECTRA ;  OXIDATION ;  COMPLEXES ;  ZEOLITES
语种: 英语
WOS记录号: WOS:000238805500001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140359
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Gao, Xiaohan,Xu, Jie. A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol[J]. APPLIED CLAY SCIENCE,2006,33(1):1-6.
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