中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: 1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude
作者: Xiao, Fengping;  Wang, Jianbo
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2006-07-21
DOI: 10.1021/jo0605391
卷: 71, 期:15, 页:5789-5791
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A series of diazo carbonyl compounds bearing different substituents have been prepared in order to investigate the steric effect in 1,2-migration reaction of rhodium(II) carbene. Through the investigation on the diazo decomposition of these compounds with Rh-2(OAc)(4), it was found that the steric effect could dramatically influence the migratory aptitude. In many cases, the steric effect could override the inherent electronic effect of the substituent.
关键词[WOS]: DIAZO CARBONYL-COMPOUNDS ;  ACID-CATALYZED REACTIONS ;  DECOMPOSITION ;  ESTERS ;  REARRANGEMENT ;  CONDENSATION ;  ALDEHYDES ;  KDO
语种: 英语
WOS记录号: WOS:000239017500049
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140365
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Xiao, Fengping,Wang, Jianbo. 1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude[J]. JOURNAL OF ORGANIC CHEMISTRY,2006,71(15):5789-5791.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xiao, Fengping]'s Articles
 [Wang, Jianbo]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xiao, Fengping]‘s Articles
 [Wang, Jianbo]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace