DICP OpenIR
Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst
Yan, L; Ding, YJ; Zhu, HJ; Yin, HM; Jiao, GP; Zhao, DY; Lin, LW
关键词Triphenyl Phosphine Rhodium Mesostructured Cellular Foam Supported Catalyst Propylene Hydroformylation
刊名CHINESE JOURNAL OF CATALYSIS
2006
27期:1页:1-3
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
英文摘要Siliceous mesostructured cellular foams (MCFs) are a new class of three-dimensional hydrothermally robust materials with ultralarge mesopores. The open system of large pores and the controllable pore size give MCFs unique advantages as catalyst supports. In this paper, MCFs were employed as supports in developing the PPh3-Rh/MCF catalyst for propylene hydroformylation in a fixed-bed reactor. The PPh3-Rh/MCF catalyst shows high activity (propylene conversion of 21.6% and butyraldehyde TOF of 160.6 h(-1)), high selectivity (n-butyraldehyde/i-butyraldehyde = 10.4), and excellent stability under mild conditions of p = 1.0 MPa, T 393 K, and SV = 2 000 h(-1).
语种英语
WOS记录号WOS:000235437700001
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140367
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
推荐引用方式
GB/T 7714
Yan, L,Ding, YJ,Zhu, HJ,et al. Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2006,27(1):1-3.
APA Yan, L.,Ding, YJ.,Zhu, HJ.,Yin, HM.,Jiao, GP.,...&Lin, LW.(2006).Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst.CHINESE JOURNAL OF CATALYSIS,27(1),1-3.
MLA Yan, L,et al."Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst".CHINESE JOURNAL OF CATALYSIS 27.1(2006):1-3.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Yan, L]的文章
[Ding, YJ]的文章
[Zhu, HJ]的文章
百度学术
百度学术中相似的文章
[Yan, L]的文章
[Ding, YJ]的文章
[Zhu, HJ]的文章
必应学术
必应学术中相似的文章
[Yan, L]的文章
[Ding, YJ]的文章
[Zhu, HJ]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。