DICP OpenIR
Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst
Yan, L; Ding, YJ; Zhu, HJ; Yin, HM; Jiao, GP; Zhao, DY; Lin, LW
KeywordTriphenyl Phosphine Rhodium Mesostructured Cellular Foam Supported Catalyst Propylene Hydroformylation
Source PublicationCHINESE JOURNAL OF CATALYSIS
2006
Volume27Issue:1Pages:1-3
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
AbstractSiliceous mesostructured cellular foams (MCFs) are a new class of three-dimensional hydrothermally robust materials with ultralarge mesopores. The open system of large pores and the controllable pore size give MCFs unique advantages as catalyst supports. In this paper, MCFs were employed as supports in developing the PPh3-Rh/MCF catalyst for propylene hydroformylation in a fixed-bed reactor. The PPh3-Rh/MCF catalyst shows high activity (propylene conversion of 21.6% and butyraldehyde TOF of 160.6 h(-1)), high selectivity (n-butyraldehyde/i-butyraldehyde = 10.4), and excellent stability under mild conditions of p = 1.0 MPa, T 393 K, and SV = 2 000 h(-1).
Language英语
WOS IDWOS:000235437700001
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140367
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Recommended Citation
GB/T 7714
Yan, L,Ding, YJ,Zhu, HJ,et al. Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2006,27(1):1-3.
APA Yan, L.,Ding, YJ.,Zhu, HJ.,Yin, HM.,Jiao, GP.,...&Lin, LW.(2006).Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst.CHINESE JOURNAL OF CATALYSIS,27(1),1-3.
MLA Yan, L,et al."Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst".CHINESE JOURNAL OF CATALYSIS 27.1(2006):1-3.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yan, L]'s Articles
[Ding, YJ]'s Articles
[Zhu, HJ]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yan, L]'s Articles
[Ding, YJ]'s Articles
[Zhu, HJ]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yan, L]'s Articles
[Ding, YJ]'s Articles
[Zhu, HJ]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.