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题名: State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation
作者: Zhang, JY;  Dai, DX;  Wang, CC;  Harich, SA;  Wang, XY;  Yang, XM;  Gustafsson, M;  Skodje, RT
刊名: PHYSICAL REVIEW LETTERS
发表日期: 2006-03-10
DOI: 10.1103/PhysRevLett.96.093201
卷: 96, 期:9
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Multidisciplinary
研究领域[WOS]: Physics
英文摘要: The influence of reagent rotation on the dynamics of the D+H-2-> HD+H reaction is studied. The state-resolved differential cross section is measured using the Rydberg-atom scheme in a crossed beam experiment. It is found that the H-2 rotation has a strong influence on the results. This effect was traced to the selection of the quantum bottleneck states through reagent orientation, thus suggesting a novel strategy to control the transition-state pathways in direct chemical reactions.
关键词[WOS]: SPECTRAL QUANTIZATION ;  CROSS-SECTIONS ;  SCATTERING ;  DISTRIBUTIONS ;  RESONANCES ;  BARRIERS ;  ROTATION ;  H+H2
语种: 英语
WOS记录号: WOS:000235905700018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140369
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
3.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

Recommended Citation:
Zhang, JY,Dai, DX,Wang, CC,et al. State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation[J]. PHYSICAL REVIEW LETTERS,2006,96(9).
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