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State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation
Zhang, JY; Dai, DX; Wang, CC; Harich, SA; Wang, XY; Yang, XM; Gustafsson, M; Skodje, RT
Source PublicationPHYSICAL REVIEW LETTERS
2006-03-10
DOI10.1103/PhysRevLett.96.093201
Volume96Issue:9
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Multidisciplinary
WOS Research AreaPhysics
WOS KeywordSPECTRAL QUANTIZATION ; CROSS-SECTIONS ; SCATTERING ; DISTRIBUTIONS ; RESONANCES ; BARRIERS ; ROTATION ; H+H2
AbstractThe influence of reagent rotation on the dynamics of the D+H-2-> HD+H reaction is studied. The state-resolved differential cross section is measured using the Rydberg-atom scheme in a crossed beam experiment. It is found that the H-2 rotation has a strong influence on the results. This effect was traced to the selection of the quantum bottleneck states through reagent orientation, thus suggesting a novel strategy to control the transition-state pathways in direct chemical reactions.
Language英语
WOS IDWOS:000235905700018
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140369
Collection中国科学院大连化学物理研究所
Affiliation1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
3.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
Recommended Citation
GB/T 7714
Zhang, JY,Dai, DX,Wang, CC,et al. State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation[J]. PHYSICAL REVIEW LETTERS,2006,96(9).
APA Zhang, JY.,Dai, DX.,Wang, CC.,Harich, SA.,Wang, XY.,...&Skodje, RT.(2006).State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation.PHYSICAL REVIEW LETTERS,96(9).
MLA Zhang, JY,et al."State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation".PHYSICAL REVIEW LETTERS 96.9(2006).
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