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Molybdenum deposition on the thin alumina film: A combinatorial investigation by HREELS, XPS and UPS
Jiang, Zhiquan; Huang, Weixin; Zhang, Zhen; Zhao, Hong; Tan, Dali; Bao, Xinhe
刊名CHEMICAL PHYSICS LETTERS
2007-05-11
DOI10.1016/j.cplett.2007.03.078
439期:4-6页:313-317
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]SURFACES THERMAL-DESORPTION ; MODEL CATALYSTS ; ELECTRONIC-STRUCTURE ; AL2O3 FILMS ; PHOTOEMISSION ; CLUSTERS ; CO ; DECOMPOSITION ; ADSORPTION ; SUBSTRATE
英文摘要Molybdenum deposition on the thin alumina film was investigated by HREELS, XPS and UPS. HREELS and XPS results show that a strong interaction occurs between the molybdenum and the oxide, and the electron transfers from the metallic nanoparticles to the underlying substrate. UPS measurements demonstrate that the Mo 4d valence band edge of the metallic nanoparticles locates at 1.36 eV, far below the Fermi level of the bulk molybdenum. This unique electronic structure of the metallic nanoparticles may provide a totally different property from the corresponding bulk materials, indicating a significant nanometer size effect. (C) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000246880200010
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140403
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China
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GB/T 7714
Jiang, Zhiquan,Huang, Weixin,Zhang, Zhen,et al. Molybdenum deposition on the thin alumina film: A combinatorial investigation by HREELS, XPS and UPS[J]. CHEMICAL PHYSICS LETTERS,2007,439(4-6):313-317.
APA Jiang, Zhiquan,Huang, Weixin,Zhang, Zhen,Zhao, Hong,Tan, Dali,&Bao, Xinhe.(2007).Molybdenum deposition on the thin alumina film: A combinatorial investigation by HREELS, XPS and UPS.CHEMICAL PHYSICS LETTERS,439(4-6),313-317.
MLA Jiang, Zhiquan,et al."Molybdenum deposition on the thin alumina film: A combinatorial investigation by HREELS, XPS and UPS".CHEMICAL PHYSICS LETTERS 439.4-6(2007):313-317.
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