DICP OpenIR
Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation
Bi, Weibin; Xu, Xiling; Huang, Jiangou; Xiao, Daoqing; Tang, Zichao; Zhu, Qihe
关键词(Hi)(m)(h(2)o)(n) Clusters Photodissociation Photofragment Translational Spectroscopy Ab-initio Calculation
刊名ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
2007
DOI10.1524/zpch.2007.221.6.815
221期:6页:815-824
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN IODIDE ; PHOTODISSOCIATION DYNAMICS ; HI PHOTODISSOCIATION ; DOPPLER SPECTROSCOPY ; WATER CLUSTERS ; STATES ; DISSOCIATION ; BAND ; NM ; ABSORPTION
英文摘要The photodissociation of the clusters (HI)(m)(H(2)O)(n) in the supersonic molecular beam has been investigated at 281.73 nm and 280.99 nm by photofragment translational spectroscopy (PTS). The translational energy distributions of the photofragment I* ((2)P(1/2)) show that the photodissociated species is mainly HI(H(2)O)(n) (n >= 4) clusters. In addition, the structures and the relative stability of (HI)(m), (H(2)O)(n) and (HI)(m) (H(2)O)(n) (m = 1 similar to 4, n = 1 similar to 6) clusters have been obtained by ab initio calculation (the Density Functional Theory). The conclusion of the theoretical analysis is agreeable with the experimental results. So these results indicate that PTS combining theoretical calculation can be used as a new, indirect way to judge the composition of the clusters which are easy to be dissociated and difficult to be detected by mass spectroscopy.
语种英语
WOS记录号WOS:000248547100005
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140424
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Bi, Weibin,Xu, Xiling,Huang, Jiangou,et al. Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS,2007,221(6):815-824.
APA Bi, Weibin,Xu, Xiling,Huang, Jiangou,Xiao, Daoqing,Tang, Zichao,&Zhu, Qihe.(2007).Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation.ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS,221(6),815-824.
MLA Bi, Weibin,et al."Study on the (HI)(m)(H(2)O)(n) clusters by photofragment translational spectroscopy and ab-initio calculation".ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS 221.6(2007):815-824.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Bi, Weibin]的文章
[Xu, Xiling]的文章
[Huang, Jiangou]的文章
百度学术
百度学术中相似的文章
[Bi, Weibin]的文章
[Xu, Xiling]的文章
[Huang, Jiangou]的文章
必应学术
必应学术中相似的文章
[Bi, Weibin]的文章
[Xu, Xiling]的文章
[Huang, Jiangou]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。