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题名: DISCUSSION ON THE T-V PROCESS IN CN RADICAL WITH HIGH TRANSLATION ENERGY (1.5eV)
作者: Li Xuechu1;  Jackson, W. M.2
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1988
DOI: 10.3866/PKU.WHXB19880319
卷: 4, 期:3, 页:325-328
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The vibrational distributions of CNX2 Sigma(+) have been obtained in photolysis of BrCN at 193 nm. An obvious increase of nu '' = 1 population was found with increasing the collision of CN and BrCN. The populations in the nu '' = 2-5 also appeared after the tens collisions, The case can not be found in photolysis of CICN. A possible explanation was suggested that the CN radical is excited vibrationally due to a recoil which occurs at the collision of CN X-2 Sigma(+), nu '' = 0 radical carrying 1.5eV energy with the heavy molecule BrCN. This is similar to the vibrational excitation of CO at collision with a high speed H atom.
语种: 英语
WOS记录号: WOS:000207571400019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140433
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Beijing 100864, Peoples R China
2.Univ Calif Davis, Davis, CA 95616 USA

Recommended Citation:
Li Xuechu,Jackson, W. M.. DISCUSSION ON THE T-V PROCESS IN CN RADICAL WITH HIGH TRANSLATION ENERGY (1.5eV)[J]. ACTA PHYSICO-CHIMICA SINICA,1988,4(3):325-328.
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