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Thermal stability and kinetics of thermal decomposition for protionamide
Wang Shao-Xu; Zhao Zhe; Tan Zhi-Cheng; Li Yan-Sheng; Tong Bo; Shi Quan; Li Ying
KeywordProtionamide Kinetics Of Thermal Decomposition Thermogravimetry Differential Thermal Analysis Thermodynamic Property
Source PublicationACTA PHYSICO-CHIMICA SINICA
2007-09-01
DOI10.3866/PKU.WHXB20070929
Volume23Issue:9Pages:1459-1462
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
AbstractThe thermal stability and the kinetics of thermal decomposition of protionamide were studied by thermogravimetry. Activation energy E-a of thermal decomposition of this substance was obtained to be 54.65 kJ center dot mol(-1) by Kissinger method and Ozawa-Flynn-Wall method. Kinetics model function and frequency factor A of protionamide were predicted with the Malek method, which were f(alpha)=alpha(0.391)(1-alpha)(0.145) and InA=13.12, respectively. Moreover, melting point, molar enthalpy and entropy of fusion of this compound were determined to be 414.09 K, 23.21 kJ center dot mol(-1), and 56.06 J center dot mol(-1) center dot K-1, respectively.
Language英语
WOS IDWOS:000249570000029
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140447
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Jiaotong Univ, Coll Environm Sci & Chem Engn, Dalian 116028, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wang Shao-Xu,Zhao Zhe,Tan Zhi-Cheng,et al. Thermal stability and kinetics of thermal decomposition for protionamide[J]. ACTA PHYSICO-CHIMICA SINICA,2007,23(9):1459-1462.
APA Wang Shao-Xu.,Zhao Zhe.,Tan Zhi-Cheng.,Li Yan-Sheng.,Tong Bo.,...&Li Ying.(2007).Thermal stability and kinetics of thermal decomposition for protionamide.ACTA PHYSICO-CHIMICA SINICA,23(9),1459-1462.
MLA Wang Shao-Xu,et al."Thermal stability and kinetics of thermal decomposition for protionamide".ACTA PHYSICO-CHIMICA SINICA 23.9(2007):1459-1462.
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