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Thermal stability and kinetics of thermal decomposition for protionamide
Wang Shao-Xu; Zhao Zhe; Tan Zhi-Cheng; Li Yan-Sheng; Tong Bo; Shi Quan; Li Ying
关键词Protionamide Kinetics Of Thermal Decomposition Thermogravimetry Differential Thermal Analysis Thermodynamic Property
刊名ACTA PHYSICO-CHIMICA SINICA
2007-09-01
DOI10.3866/PKU.WHXB20070929
23期:9页:1459-1462
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The thermal stability and the kinetics of thermal decomposition of protionamide were studied by thermogravimetry. Activation energy E-a of thermal decomposition of this substance was obtained to be 54.65 kJ center dot mol(-1) by Kissinger method and Ozawa-Flynn-Wall method. Kinetics model function and frequency factor A of protionamide were predicted with the Malek method, which were f(alpha)=alpha(0.391)(1-alpha)(0.145) and InA=13.12, respectively. Moreover, melting point, molar enthalpy and entropy of fusion of this compound were determined to be 414.09 K, 23.21 kJ center dot mol(-1), and 56.06 J center dot mol(-1) center dot K-1, respectively.
语种英语
WOS记录号WOS:000249570000029
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140447
专题中国科学院大连化学物理研究所
作者单位1.Dalian Jiaotong Univ, Coll Environm Sci & Chem Engn, Dalian 116028, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China
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Wang Shao-Xu,Zhao Zhe,Tan Zhi-Cheng,et al. Thermal stability and kinetics of thermal decomposition for protionamide[J]. ACTA PHYSICO-CHIMICA SINICA,2007,23(9):1459-1462.
APA Wang Shao-Xu.,Zhao Zhe.,Tan Zhi-Cheng.,Li Yan-Sheng.,Tong Bo.,...&Li Ying.(2007).Thermal stability and kinetics of thermal decomposition for protionamide.ACTA PHYSICO-CHIMICA SINICA,23(9),1459-1462.
MLA Wang Shao-Xu,et al."Thermal stability and kinetics of thermal decomposition for protionamide".ACTA PHYSICO-CHIMICA SINICA 23.9(2007):1459-1462.
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