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题名: Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl-2 center dot 6H(2)O
作者: Liu, B. P.;  Lv, X. C.;  Tan, Z. C.;  Zhang, Z. H.;  Shi, Q.;  Yang, L. N.;  Xing, J.;  Sun, L. X.;  Zhang, T.
关键词: adiabatic calorimetry ;  L-aspartic acid ;  DSC ;  heat capacity ;  Ho(Asp)Cl-2 center dot 6H2O ;  TG-DTG ;  thermal analysis
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2007-07-01
卷: 89, 期:1, 页:283-287
收录类别: ISTP ;  SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The molar heat capacity, C (p,m), of a complex of holmium chloride coordinated with L-aspartic acid, Ho(Asp)Cl-2 center dot 6H(2)O, was measured from 80 to 397 K with an automated adiabatic calorimeter. The thermodynamic functions H (T)-H (298.15) and S (T)-S (298.15) were derived from 80 to 395 K with temperature interval of 5 K. The thermal stability of the complex was investigated by differential scanning calorimeter (DSC) and thermogravimetric (TG) technique, and the mechanism of thermal decomposing of the complex was determined based on the structure and the thermal analysis experiment.
关键词[WOS]: ADIABATIC CALORIMETER ;  ENTHALPY ;  HYDRATE ;  ACID
语种: 英语
WOS记录号: WOS:000247991700041
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140463
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
2.Hunan Univ Arts & Sci, Dept Chem, Changde 415000, Peoples R China
3.Dalian Univ Technol, Coll Environm & Chem Engn, Dalian 116023, Peoples R China

Recommended Citation:
Liu, B. P.,Lv, X. C.,Tan, Z. C.,et al. Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl-2 center dot 6H(2)O[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2007,89(1):283-287.
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