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题名: 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds
作者: Xi, Zhenfeng
刊名: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
发表日期: 2007-06-15
DOI: 10.1246/bcsj.80.1021
卷: 80, 期:6, 页:1021-1032
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: In this account, our recent results on the application of substituted 1-lithio-1,3-dienes as building blocks for the preparation of a wide variety of cyclic compounds and linear compounds are briefly summarized. Results have revealed that the essential factor which makes 1-lithio-1,3-diene derivatives useful and unique as building blocks is the intracooperation between the alkenyllithium moiety and the butadienyl skeleton, notwithstanding that the alkenyllithium moiety itself reacts with organic substrates in the usual way. In addition, the substitution patterns and the nature of the substituents on the butadienyl skeleton have been demonstrated to affect remarkably the reaction pathways of 1-lithio-1,3-diene derivatives.
关键词[WOS]: MULTIPLY SUBSTITUTED CYCLOPENTADIENES ;  TEMPORARY SILICON CONNECTION ;  PI-CONJUGATED SYSTEMS ;  ANIONIC RING-CLOSURE ;  EFFICIENT SYNTHESIS ;  ELECTROPHILIC CYCLIZATION ;  COUPLING REACTIONS ;  6-SUBSTITUTED PHENANTHRIDINES ;  SYNTHETIC APPLICATIONS ;  GROUP-14 METALLOLES
语种: 英语
WOS记录号: WOS:000248256600001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140464
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Xi, Zhenfeng. 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,2007,80(6):1021-1032.
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