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1-lithio-1,3-dienes: Useful building blocks for cyclic compounds
Xi, Zhenfeng
刊名BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
2007-06-15
DOI10.1246/bcsj.80.1021
80期:6页:1021-1032
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]MULTIPLY SUBSTITUTED CYCLOPENTADIENES ; TEMPORARY SILICON CONNECTION ; PI-CONJUGATED SYSTEMS ; ANIONIC RING-CLOSURE ; EFFICIENT SYNTHESIS ; ELECTROPHILIC CYCLIZATION ; COUPLING REACTIONS ; 6-SUBSTITUTED PHENANTHRIDINES ; SYNTHETIC APPLICATIONS ; GROUP-14 METALLOLES
英文摘要In this account, our recent results on the application of substituted 1-lithio-1,3-dienes as building blocks for the preparation of a wide variety of cyclic compounds and linear compounds are briefly summarized. Results have revealed that the essential factor which makes 1-lithio-1,3-diene derivatives useful and unique as building blocks is the intracooperation between the alkenyllithium moiety and the butadienyl skeleton, notwithstanding that the alkenyllithium moiety itself reacts with organic substrates in the usual way. In addition, the substitution patterns and the nature of the substituents on the butadienyl skeleton have been demonstrated to affect remarkably the reaction pathways of 1-lithio-1,3-diene derivatives.
语种英语
WOS记录号WOS:000248256600001
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140464
专题中国科学院大连化学物理研究所
作者单位Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
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Xi, Zhenfeng. 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,2007,80(6):1021-1032.
APA Xi, Zhenfeng.(2007).1-lithio-1,3-dienes: Useful building blocks for cyclic compounds.BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,80(6),1021-1032.
MLA Xi, Zhenfeng."1-lithio-1,3-dienes: Useful building blocks for cyclic compounds".BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 80.6(2007):1021-1032.
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