DICP OpenIR
1-lithio-1,3-dienes: Useful building blocks for cyclic compounds
Xi, Zhenfeng
Source PublicationBULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
2007-06-15
DOI10.1246/bcsj.80.1021
Volume80Issue:6Pages:1021-1032
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMULTIPLY SUBSTITUTED CYCLOPENTADIENES ; TEMPORARY SILICON CONNECTION ; PI-CONJUGATED SYSTEMS ; ANIONIC RING-CLOSURE ; EFFICIENT SYNTHESIS ; ELECTROPHILIC CYCLIZATION ; COUPLING REACTIONS ; 6-SUBSTITUTED PHENANTHRIDINES ; SYNTHETIC APPLICATIONS ; GROUP-14 METALLOLES
AbstractIn this account, our recent results on the application of substituted 1-lithio-1,3-dienes as building blocks for the preparation of a wide variety of cyclic compounds and linear compounds are briefly summarized. Results have revealed that the essential factor which makes 1-lithio-1,3-diene derivatives useful and unique as building blocks is the intracooperation between the alkenyllithium moiety and the butadienyl skeleton, notwithstanding that the alkenyllithium moiety itself reacts with organic substrates in the usual way. In addition, the substitution patterns and the nature of the substituents on the butadienyl skeleton have been demonstrated to affect remarkably the reaction pathways of 1-lithio-1,3-diene derivatives.
Language英语
WOS IDWOS:000248256600001
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140464
Collection中国科学院大连化学物理研究所
AffiliationPeking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Xi, Zhenfeng. 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,2007,80(6):1021-1032.
APA Xi, Zhenfeng.(2007).1-lithio-1,3-dienes: Useful building blocks for cyclic compounds.BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,80(6),1021-1032.
MLA Xi, Zhenfeng."1-lithio-1,3-dienes: Useful building blocks for cyclic compounds".BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 80.6(2007):1021-1032.
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