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Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel
Wei, Qiang; Sun, Ju-Long; Yue, Xian-Fang; Yin, Hong-Ming; Han, Ke-Li
Source PublicationCHEMICAL PHYSICS LETTERS
2007-11-05
DOI10.1016/j.cplett.2007.09.069
Volume448Issue:1-3Pages:11-15
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordACETIC-ACID ; STATE DISTRIBUTIONS ; ABSORPTION-SPECTRUM ; ACRYLIC-ACID ; S-2 STATE ; DISSOCIATION ; TRANSITIONS ; CH3ONO ; JET
AbstractThe photodissociation dynamics of benzoic acid monomer at 266 nm is investigated by probing the nascent OH photoproduct using the laser-induced-fluorescence (LIF) technique. The nascent OH radical is distributed in the ground vibrational state and the rotational temperature is 620 +/- 30 K. The F, ((2)Pi(3/2)) and F-2 ((2)Pi(1/2)) spin-orbit states of OH photofragment are unstatistically populated, and Lambda-doublet levels are not equally populated. The present study associated with the available dynamics information predicts that OH radical is mainly produced from benzoic acid monomer on the T-2 energy surface. (c) 2007 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000251230000004
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140466
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wei, Qiang,Sun, Ju-Long,Yue, Xian-Fang,et al. Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel[J]. CHEMICAL PHYSICS LETTERS,2007,448(1-3):11-15.
APA Wei, Qiang,Sun, Ju-Long,Yue, Xian-Fang,Yin, Hong-Ming,&Han, Ke-Li.(2007).Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel.CHEMICAL PHYSICS LETTERS,448(1-3),11-15.
MLA Wei, Qiang,et al."Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel".CHEMICAL PHYSICS LETTERS 448.1-3(2007):11-15.
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