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题名: Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel
作者: Wei, Qiang;  Sun, Ju-Long;  Yue, Xian-Fang;  Yin, Hong-Ming;  Han, Ke-Li
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2007-11-05
DOI: 10.1016/j.cplett.2007.09.069
卷: 448, 期:1-3, 页:11-15
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The photodissociation dynamics of benzoic acid monomer at 266 nm is investigated by probing the nascent OH photoproduct using the laser-induced-fluorescence (LIF) technique. The nascent OH radical is distributed in the ground vibrational state and the rotational temperature is 620 +/- 30 K. The F, ((2)Pi(3/2)) and F-2 ((2)Pi(1/2)) spin-orbit states of OH photofragment are unstatistically populated, and Lambda-doublet levels are not equally populated. The present study associated with the available dynamics information predicts that OH radical is mainly produced from benzoic acid monomer on the T-2 energy surface. (c) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: ACETIC-ACID ;  STATE DISTRIBUTIONS ;  ABSORPTION-SPECTRUM ;  ACRYLIC-ACID ;  S-2 STATE ;  DISSOCIATION ;  TRANSITIONS ;  CH3ONO ;  JET
语种: 英语
WOS记录号: WOS:000251230000004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140466
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Wei, Qiang,Sun, Ju-Long,Yue, Xian-Fang,et al. Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel[J]. CHEMICAL PHYSICS LETTERS,2007,448(1-3):11-15.
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