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Probing the ultrafast photoelectron spectra of Br-2 molecule
Hu, Jie; Liu, Feng; Meng, Qing-Tian; Han, Ke-Li
关键词Time-dependent-wave-packet Photoelectron Spectra Dissociation
刊名INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
2007-08-15
DOI10.1002/qua.21364
107期:10页:1994-1998
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Mathematics, Interdisciplinary Applications ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Mathematics ; Physics
关键词[WOS]MULTIPHOTON IONIZATION ; DYNAMICS ; DISSOCIATION ; SPECTROSCOPY ; PULSES ; PHASE ; NA2 ; BR2
英文摘要The time-dependent-wave-packet method is applied to study the ionization of Br-2 molecule with four ionization processes. The ground state absorption makes the photoelectron to be left in the three final ionic states: Br-2(+) (X-2 Sigma(+)(g)), Br-2(+) (A(2)Pi(u)), and Br-2(+) (B-2 Sigma(+)(u)), and each population of these ionic states is related with the laser intensities. The information of the dissociation can be got by analyzing the photoelectron features of the transient wave packet, which also suggests that an ionization process occurs during the dissociation, and the Br atoms that mainly resulted from the dissociation of Br-2 (C-1 Pi(u)) are ionized at later time delays as the dissociation is nearly complete. (c) 2007 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000247155900007
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140468
专题中国科学院大连化学物理研究所
作者单位1.Dalian Maritime Univ, Dept Phys, Dalian 116026, Peoples R China
2.Dalian Naval Acad, Dept Basic Sci, Dalian 116001, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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GB/T 7714
Hu, Jie,Liu, Feng,Meng, Qing-Tian,et al. Probing the ultrafast photoelectron spectra of Br-2 molecule[J]. INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY,2007,107(10):1994-1998.
APA Hu, Jie,Liu, Feng,Meng, Qing-Tian,&Han, Ke-Li.(2007).Probing the ultrafast photoelectron spectra of Br-2 molecule.INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY,107(10),1994-1998.
MLA Hu, Jie,et al."Probing the ultrafast photoelectron spectra of Br-2 molecule".INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 107.10(2007):1994-1998.
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