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题名: Synthesis and crystal structure of [1,3-N,N-bis{2,6-diisopropylphenyl}imidazol-2-ylidene]chloro-[N,N-dimethylbenzylamine-2-C,N]palladium(II)
作者: Cao, Xin-Hua;  Zheng, Ying;  Yu, Hong-Wei;  Shi, Ji-Cheng
关键词: N-heterocyclic carbene ;  cyclopalladation ;  X-ray structure
刊名: JOURNAL OF COORDINATION CHEMISTRY
发表日期: 2007-01-20
DOI: 10.1080/00958970600763557
卷: 60, 期:2, 页:207-211
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: The title compound 1 has been synthesized and its structure has been determined by singlecrystal X-ray methods. Crystal data: C36H48ClN3Pd, M = 664.62, monoclinic, space group P2(1)/ n with a = 11.857(5), b = 21.042(8), c = 14.632(6) angstrom, beta = 106.492(5), Z = 4, V = 3501(2) angstrom(3), D-c = 1.261 g cm(-3), mu(Mo-K alpha) = 0.633mm(-1), F(000) = 1392; final R and wR = 0.0412 and 0.0889, respectively, for 3265 observed reflections with I >= 2 sigma(I). The Pd(II) atom has distorted square planar geometry, due to the bulk of the isopropyl groups on the NHC ligand. Positioning of the carbenic carbon trans to the amino group and the metalated carbon trans to chlorine is consist with the trans influence.
关键词[WOS]: PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM ;  OLEFIN METATHESIS CATALYSTS ;  CROSS-COUPLING REACTIONS ;  N-HETEROCYCLIC CARBENES ;  ARYL CHLORIDES ;  COMPLEXES ;  HYDROGENATION ;  AMINATION ;  BROMIDES ;  LIGANDS
语种: 英语
WOS记录号: WOS:000243171500011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140469
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Cao, Xin-Hua,Zheng, Ying,Yu, Hong-Wei,et al. Synthesis and crystal structure of [1,3-N,N-bis{2,6-diisopropylphenyl}imidazol-2-ylidene]chloro-[N,N-dimethylbenzylamine-2-C,N]palladium(II)[J]. JOURNAL OF COORDINATION CHEMISTRY,2007,60(2):207-211.
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