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题名: Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O
作者: Lu Ji-Lin;  Liu Bei-Ping;  Tan Zhi-Cheng;  Mang Da-Shun;  Chen Yuan-Dao;  Li Lin
关键词: thermochemistry ;  low temperature heat capacity ;  standard enthalpy of formation ;  samarium chloride-glycine complex
刊名: CHINESE JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2007-09-01
卷: 23, 期:9, 页:1639-1643
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: A complex of samarium with glymine, [Sm(Gly)(2)Cl-3-3H(2)O], was synthesized and characterized by DSC, TG and DTG. A possible mechanism of thermal decomposition of this complex was suggested. The heat capacities of the complex were measured by a precision adiabatic calorimeter over the temperature range from 82 to 375 K. The solution enthalpies of reactants [SmCl3.6H(2)O +2Gly] and the products [Sm (Gly)(2)Cl-3.3H(2)O +3H(2)O] were determined by an isoperibel solution- reaction calorimeter at 298.15 K, respectively; the standard molar enthalpy of formation of [Sm(Gly)(2)Cl-3.3H(2)O] was calculated through a designed thermochemical cycle.
语种: 英语
WOS记录号: WOS:000249881900026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140470
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,et al. Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2007,23(9):1639-1643.
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