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题名: Honeycomb-like layered cobalt(II) phosphonate with [O2CCH(OH)PO3](3-) as ligand: Hydrothermal synthesis, crystal structure, and magnetic properties
作者: Zhang, Yang-Yang;  Zeng, Ming-Hua;  Qi, Yue;  Sang, Shi-Yun;  Liu, Zhong-Min
关键词: cobalt(II) phosphonate ;  hydrothermal synthesis ;  magnetic properties
刊名: INORGANIC CHEMISTRY COMMUNICATIONS
发表日期: 2007
DOI: 10.1016/j.inoche.2006.08.016
卷: 10, 期:1, 页:33-36
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: A new cobalt(II) phosphonate, [enH(2)](0.5)[CO(Pa)(H2O)]center dot H2O (1) (H(3)pa = hydroxy-phosphono-acetic acid, HO2CCH(OH)PO3H2; en = ethylenediamine), has been hydrothermally synthesized and structurally characterized. Compound 1 has a honeycomb-like layer structure which is composed Of CoO6 octahedra and mu(3)-pa ligands with the protonated en and lattice water molecules stabilized between the layers. Magnetic studies indicate that 1 shows weak ferromagnetic behavior, spin-glass behavior, and metamagnetic behavior. (c) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: WEAK FERROMAGNETISM ;  OPEN-FRAMEWORK ;  DIPHOSPHONATE ;  TRANSITION ;  CHANNELS ;  CO(II)
语种: 英语
WOS记录号: WOS:000243676000008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140483
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Appl Catalysis Lab, Dalian 116023, Peoples R China
2.GuangXi Normal Univ, Dept Chem & Chem Engn, Guilin 541004, Peoples R China

Recommended Citation:
Zhang, Yang-Yang,Zeng, Ming-Hua,Qi, Yue,et al. Honeycomb-like layered cobalt(II) phosphonate with [O2CCH(OH)PO3](3-) as ligand: Hydrothermal synthesis, crystal structure, and magnetic properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2007,10(1):33-36.
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