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The electrochemical properties of Ti0.9Zr0.2Mn1.5Cr0.3V0.3-x wt% La0.7Mg0.25Zr0.05Ni2.975Co0.525 (x=0, 5, 10) hydrogen storage composite electrodes
Chu, Hai-Liang; Zhang, Yao; Sun, Li-Xian; Qiu, Shu-Jun; Xu, Fen; Yuan, Hua-Tang
KeywordHydrogen Storage Electrodes Ti-mn-based Laves Phase Alloy Surface Modification Electrochemical Properties Ball Milling La-mg-based Alloy
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2007-08-01
DOI10.1016/j.ijhydene.2006.09.015
Volume32Issue:12Pages:1898-1904
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS KeywordLAVES PHASE ALLOYS ; METAL HYDRIDE ELECTRODES ; NANOPARTICLES ; MECHANISM ; POWDER
AbstractIn the present work, new type hydrogen storage composites electrodes Ti0.9Zr0.2Mn1.5Cr0.3V0.3-x wt% La0.7Mg0.25Zr0.05Ni2.975 Co-0.525 (x = 0, 5, 10) were successively prepared by ball milling method. The structure and electrochemical properties of the composites were investigated by means of XRD, SEM, EDS and electrochemical measurements. It was found that the bulk of the composites still retained the hexagonal C14 Laves structure after short-term ball milling and that the maximum capacity of the composite electrodes was significantly improved to 292.4 and 314.0mA h/g for x =5 and 10, respectively, from maximum 48.6mA h/g of Ti0.9Zr0.2Mn1.5Cr0.3V0.3 alloy electrode. Electrochemical impedance spectra and cyclic voltammograms (CV) measurements revealed that the charge-transfer resistance was reduced with increasing amount of La-Mg-based alloy. The increasing x amount also lifted the values of hydrogen diffusion coefficient D of the composite electrodes obtained by anodic polarization (AP) measurements. These indicated that the La-Mg-based alloy as a surface modifier not only increased the discharge capacity but also improved the charge-discharge kinetics of composite electrode greatly. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000249739100037
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140506
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Chu, Hai-Liang,Zhang, Yao,Sun, Li-Xian,et al. The electrochemical properties of Ti0.9Zr0.2Mn1.5Cr0.3V0.3-x wt% La0.7Mg0.25Zr0.05Ni2.975Co0.525 (x=0, 5, 10) hydrogen storage composite electrodes[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2007,32(12):1898-1904.
APA Chu, Hai-Liang,Zhang, Yao,Sun, Li-Xian,Qiu, Shu-Jun,Xu, Fen,&Yuan, Hua-Tang.(2007).The electrochemical properties of Ti0.9Zr0.2Mn1.5Cr0.3V0.3-x wt% La0.7Mg0.25Zr0.05Ni2.975Co0.525 (x=0, 5, 10) hydrogen storage composite electrodes.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,32(12),1898-1904.
MLA Chu, Hai-Liang,et al."The electrochemical properties of Ti0.9Zr0.2Mn1.5Cr0.3V0.3-x wt% La0.7Mg0.25Zr0.05Ni2.975Co0.525 (x=0, 5, 10) hydrogen storage composite electrodes".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 32.12(2007):1898-1904.
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