DICP OpenIR
Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines
Wang, You-Qing; Lu, Sheng-Mei; Zhou, Yong-Gui
刊名JOURNAL OF ORGANIC CHEMISTRY
2007-05-11
DOI10.1021/jo0700878
72期:10页:3729-3734
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]N-ARYL IMINES ; CHIRAL TOLUENE-2,ALPHA-SULTAM AUXILIARIES ; IR-F-BINAPHANE ; REDUCTIVE AMINATION ; C=N BONDS ; ORGANOMETALLIC REAGENTS ; BOROHYDRIDE REDUCTION ; PRACTICAL SYNTHESIS ; SULTAM AUXILIARIES ; AROMATIC KETIMINES
英文摘要Pd/bisphosphines complexes are highly effective catalysts for asymmetric hydrogenation of activated imines in trifluoroethanol. The asymmetric hydrogenation of N-diphenylphosphinyl ketimines 3 with Pd(CF3CO2)/(S)-SegPhos indicated 87-99% ee, and N-tosylimines 5 could gave 88-97% ee with Pd(CF3CO2)/(S)-SynPhos as a catalyst. Cyclic N-sulfonylimines 7 and 11 were hydrogenated to afford the useful chiral sultam derivatives in 79-93% ee, which are important organic synthetic intermediates and structural units of agricultural and pharmaceutical agents.
语种英语
WOS记录号WOS:000246206700017
引用统计
被引频次:100[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140507
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Wang, You-Qing,Lu, Sheng-Mei,Zhou, Yong-Gui. Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines[J]. JOURNAL OF ORGANIC CHEMISTRY,2007,72(10):3729-3734.
APA Wang, You-Qing,Lu, Sheng-Mei,&Zhou, Yong-Gui.(2007).Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines.JOURNAL OF ORGANIC CHEMISTRY,72(10),3729-3734.
MLA Wang, You-Qing,et al."Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines".JOURNAL OF ORGANIC CHEMISTRY 72.10(2007):3729-3734.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, You-Qing]的文章
[Lu, Sheng-Mei]的文章
[Zhou, Yong-Gui]的文章
百度学术
百度学术中相似的文章
[Wang, You-Qing]的文章
[Lu, Sheng-Mei]的文章
[Zhou, Yong-Gui]的文章
必应学术
必应学术中相似的文章
[Wang, You-Qing]的文章
[Lu, Sheng-Mei]的文章
[Zhou, Yong-Gui]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。