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Hydrogen-bonding directed reversal of enantioselectivity
Zeng, Wei; Chen, Guo-Ying; Zhou, Yong-Gui; Li, Yu-Xue
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2007-01-31
DOI10.1021/ja067346f
129期:4页:750-751
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]1,3-DIPOLAR CYCLOADDITION REACTIONS ; CATALYZED ASYMMETRIC ALLYLATION ; SINGLE CHIRAL BACKBONE ; DIELS-ALDER REACTIONS ; AZOMETHINE YLIDES ; STEREOSELECTIVE-SYNTHESIS ; HOMOGENEOUS CATALYSIS ; COPPER(II) COMPLEXES ; ACHIRAL LIGANDS ; ALDOL ADDITIONS
英文摘要A successful stereochemical reversal was achieved in AgOAc catalyzed [3+2] cycloaddition by the formation of hydrogen bonding between ligand and reactant. This strategy provides an efficient and convenient route to prepare both enantiomers of a chiral compound. DFT studies proposed a reasonable mechanism of the reversal of the enantioselectivity; hydrogen bonding changed the transition state. The strategy may provide some useful hints for ligand design.
语种英语
WOS记录号WOS:000243683800013
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被引频次:183[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140544
专题中国科学院大连化学物理研究所
作者单位1.CAS, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.CAS, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
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Zeng, Wei,Chen, Guo-Ying,Zhou, Yong-Gui,et al. Hydrogen-bonding directed reversal of enantioselectivity[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(4):750-751.
APA Zeng, Wei,Chen, Guo-Ying,Zhou, Yong-Gui,&Li, Yu-Xue.(2007).Hydrogen-bonding directed reversal of enantioselectivity.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(4),750-751.
MLA Zeng, Wei,et al."Hydrogen-bonding directed reversal of enantioselectivity".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.4(2007):750-751.
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