DICP OpenIR
Two pseudo-N-3 ligands and the catalytic activity of their ruthenium(II) complexes in transfer hydrogenation and hydrogenation of ketones
Yu, Z. K.; Zeng, F. L.; Sun, X. J.; Deng, H. X.; Dong, J. H.; Chen, J. Z.; Wang, H. M.; Pei, C. X.
关键词N-3 Ligands Ruthenium Transfer Hydrogenation Hydrogenation Ketones
刊名JOURNAL OF ORGANOMETALLIC CHEMISTRY
2007-05-01
DOI10.1016/j.jorganchem.2007.01.058
692期:11页:2306-2313
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC TRANSFER HYDROGENATION ; OLEFIN POLYMERIZATION ; CARBON-MONOXIDE ; METAL-COMPLEXES ; TERPYRIDINE ; CHEMISTRY ; PYRIDINE ; IRON(II) ; CATIONS
英文摘要Complex RuCl2(PPh3)(iBu-BTP) (5) was synthesized by the reaction of 2,6-bis(5,6-bis(iso-butyl)-1,2,4-triazin-3-yl)pyridine (iBu-BTP) and RuCl2(PPh3)(3) in refluxing toluene, and its molecular structure was confirmed by X-ray crystallographic determination. Complex 5 was applied as a catalyst for transfer hydrogenation of ketones and exhibited catalytic activity comparable to RuCl2(PPh3)(Me4BPPy) (1) (Me4BPPy = bis(3,5-dimethylpyrazol-1-yl)pyridine) in some cases. The difference between the catalytic activity of 5 and 1 is attributed to the significantly different arrangement and positions of the PPh3 and chlorides and also to the different electron density on the N-heterocycles. Complex 1 exhibited good to excellent catalytic activity in hydrogenation of ketones under mild conditions. These results have suggested new applications of iBu-BTP and Me4BPPy as promising planar tridentate pseudo-N-3 ligands to construct highly active transition-metal catalysts. (C) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000246323300023
引用统计
被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140581
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Shenyang 110016, Liaoning, Peoples R China
3.Beijing Inst Pharmaceut Chem, Beijing 102205, Peoples R China
推荐引用方式
GB/T 7714
Yu, Z. K.,Zeng, F. L.,Sun, X. J.,et al. Two pseudo-N-3 ligands and the catalytic activity of their ruthenium(II) complexes in transfer hydrogenation and hydrogenation of ketones[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2007,692(11):2306-2313.
APA Yu, Z. K..,Zeng, F. L..,Sun, X. J..,Deng, H. X..,Dong, J. H..,...&Pei, C. X..(2007).Two pseudo-N-3 ligands and the catalytic activity of their ruthenium(II) complexes in transfer hydrogenation and hydrogenation of ketones.JOURNAL OF ORGANOMETALLIC CHEMISTRY,692(11),2306-2313.
MLA Yu, Z. K.,et al."Two pseudo-N-3 ligands and the catalytic activity of their ruthenium(II) complexes in transfer hydrogenation and hydrogenation of ketones".JOURNAL OF ORGANOMETALLIC CHEMISTRY 692.11(2007):2306-2313.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Yu, Z. K.]的文章
[Zeng, F. L.]的文章
[Sun, X. J.]的文章
百度学术
百度学术中相似的文章
[Yu, Z. K.]的文章
[Zeng, F. L.]的文章
[Sun, X. J.]的文章
必应学术
必应学术中相似的文章
[Yu, Z. K.]的文章
[Zeng, F. L.]的文章
[Sun, X. J.]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。