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题名: Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3-delta based cathode SOFCII. The effect of CO2 on the chemical stability
作者: Yan, Aiyu1, 2, 3;  Maragou, Vasiliki2;  Arico, Antonino4;  Cheng, Mojie1;  Tsiakaras, Panagiotis2
关键词: low and intermediate temperature solid oxide fuel cells ;  BSCF cathodes ;  Carbon dioxide effect
刊名: APPLIED CATALYSIS B-ENVIRONMENTAL
发表日期: 2007-11-15
DOI: 10.1016/j.apeatb.2007.06.010
卷: 76, 期:3-4, 页:320-327
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Physical ;  Engineering, Environmental ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The effect of carbon dioxide on the chemical stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-delta cathode in the real reaction environment at 450 degrees C was investigated by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), temperature programmed desorption (TPD), X-ray diffraction (XRD) and electrochemical impedance spectra (EIS) techniques. It was found that the presence even of very small quantities of CO2 seriously deteriorates the fuel cell performance at 450 degrees C. XPS, TPD and XRD results strongly evidenced the formation of carbonates involving strontium and possibly barium after the BSCF cathode was operated in 1% CO2/O-2 gas mixture at 450 degrees C for 24 h. SEM-EDX analysis of the BSCF cathode surface, after treatment in CO2/O-2 environment at 450 degrees C, showed small particles on the surface probably associated with a carbonate phase and a segregated phase of the perovskite. The corresponding EDX spectra confirmed the presence of a carbonate layer and also revealed the surface enrichment of strontium and barium elements. EIS results indicated that both ohmic and polarization resistances increased gradually with the introduction of carbon dioxide in the oxidant stream, which could be interpreted by the decreased oxygen reduction kinetics and the formation of carbonate insulating layer. (C) 2007 Elsevier B.V.. All rights reserved.
关键词[WOS]: OXIDE FUEL-CELLS ;  LOW-TEMPERATURE SOFCS ;  PEROVSKITE-TYPE OXIDES ;  THERMAL-EXPANSION ;  PERFORMANCE ;  METHANE ;  XPS ;  POLARIZATION ;  ELECTROLYTE ;  COMBUSTION
语种: 英语
WOS记录号: WOS:000251576100014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140595
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Thessaly, Sch Engn, Dept Mech Engn, Volos 38334, Greece
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
4.CNR, ITAE Inst, I-98126 Messina, Italy

Recommended Citation:
Yan, Aiyu,Maragou, Vasiliki,Arico, Antonino,et al. Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3-delta based cathode SOFCII. The effect of CO2 on the chemical stability[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2007,76(3-4):320-327.
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