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Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts
Song Wei; Shi Ruijuan; Liu Junlong; Zhan Ensheng; Li Zhanshuang; Xu Yide; Shen Wenjie
关键词Copper Iridium Palladium Ceria Alcohol Transfer Dehydrogenation
刊名CHINESE JOURNAL OF CATALYSIS
2007-02-01
28期:2页:106-108
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]TRANSFER HYDROGENATION ; SELECTIVE OXIDATION ; METAL-CATALYSTS ; OXYGEN
英文摘要Ceria-supported Cu, Ir, and Pd catalysts showed quite promising activity for transfer dehydrogenation of cyclohexanol and 2-octanol to cyclohexanone and 2-octanone, respectively, using styrene as the hydrogen acceptor. The Cu/CeO2 and Pd/CeO2 catalysts were more active than the previously reported Cu and Pd catalysts supported on Al2O3, and Ir/CeO2 exhibited extremely high activity. The reactivity of alcohols decreased in the order 2-octanol > cyclohexanol > benzyl alcohol > 1-octanol. The synergetic effect between the metals and CeO2 as well as the effective coupling of dehydrogenation of alcohols and hydrogenation of styrene was responsible for the high catalytic activity.
语种英语
WOS记录号WOS:000244994000004
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140602
专题中国科学院大连化学物理研究所
作者单位1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Song Wei,Shi Ruijuan,Liu Junlong,et al. Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(2):106-108.
APA Song Wei.,Shi Ruijuan.,Liu Junlong.,Zhan Ensheng.,Li Zhanshuang.,...&Shen Wenjie.(2007).Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts.CHINESE JOURNAL OF CATALYSIS,28(2),106-108.
MLA Song Wei,et al."Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts".CHINESE JOURNAL OF CATALYSIS 28.2(2007):106-108.
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