DICP OpenIR
Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts
Song Wei; Shi Ruijuan; Liu Junlong; Zhan Ensheng; Li Zhanshuang; Xu Yide; Shen Wenjie
KeywordCopper Iridium Palladium Ceria Alcohol Transfer Dehydrogenation
Source PublicationCHINESE JOURNAL OF CATALYSIS
2007-02-01
Volume28Issue:2Pages:106-108
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordTRANSFER HYDROGENATION ; SELECTIVE OXIDATION ; METAL-CATALYSTS ; OXYGEN
AbstractCeria-supported Cu, Ir, and Pd catalysts showed quite promising activity for transfer dehydrogenation of cyclohexanol and 2-octanol to cyclohexanone and 2-octanone, respectively, using styrene as the hydrogen acceptor. The Cu/CeO2 and Pd/CeO2 catalysts were more active than the previously reported Cu and Pd catalysts supported on Al2O3, and Ir/CeO2 exhibited extremely high activity. The reactivity of alcohols decreased in the order 2-octanol > cyclohexanol > benzyl alcohol > 1-octanol. The synergetic effect between the metals and CeO2 as well as the effective coupling of dehydrogenation of alcohols and hydrogenation of styrene was responsible for the high catalytic activity.
Language英语
WOS IDWOS:000244994000004
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140602
Collection中国科学院大连化学物理研究所
Affiliation1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Song Wei,Shi Ruijuan,Liu Junlong,et al. Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(2):106-108.
APA Song Wei.,Shi Ruijuan.,Liu Junlong.,Zhan Ensheng.,Li Zhanshuang.,...&Shen Wenjie.(2007).Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts.CHINESE JOURNAL OF CATALYSIS,28(2),106-108.
MLA Song Wei,et al."Transfer dehydrogenation of alcohols over ceria-supported Cu, Ir, and Pd catalysts".CHINESE JOURNAL OF CATALYSIS 28.2(2007):106-108.
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