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Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes
Li, Chuan-Ying; Wang, Xiao-Bing; Sun, Xiu-Li; Tang, Yong; Zheng, Jun-Cheng; Xu, Zheng-Hu; Zhou, Yong-Gui; Dai, Li-Xin
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2007-02-14
DOI10.1021/ja068642v
129期:6页:1494-+
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]WITTIG-TYPE REACTIONS ; ETHYL DIAZOACETATE ; SELECTIVE OLEFINATION ; ALDEHYDE-OLEFINATION ; STEREOSELECTIVE-SYNTHESIS ; CARBONYL-COMPOUNDS ; PHOSPHORUS YLIDES ; COMPLEX ; ESTERS ; IRON(III)
英文摘要In the presence of Ph3P and catalytic Fe(TCP) Cl, ketenes could react with EDA to give allenes in high yields under neutral conditions for the first time. By employing chiral phosphine instead of PPh3, allenes could be synthesized with high enantioselectivity (93-98% ee) in good yields.
语种英语
WOS记录号WOS:000244000700011
引用统计
被引频次:113[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140651
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Li, Chuan-Ying,Wang, Xiao-Bing,Sun, Xiu-Li,et al. Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(6):1494-+.
APA Li, Chuan-Ying.,Wang, Xiao-Bing.,Sun, Xiu-Li.,Tang, Yong.,Zheng, Jun-Cheng.,...&Dai, Li-Xin.(2007).Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(6),1494-+.
MLA Li, Chuan-Ying,et al."Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.6(2007):1494-+.
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