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题名: Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition
作者: Sun Qi1;  Gu Yuezhu1;  Guo Jingzhong1;  Ying Yongjia1;  Li Xuechu2;  Shen Guanlin2
关键词: Metastable atom ;  Dissociative excitation ;  Vibrational distribution ;  Reaction channel
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1995
DOI: 10.3866/PKU.WHXB19950107
卷: 11, 期:1, 页:31-37
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Dissociative excitation of SO2,SOCl2 through single collision with Ar(P-3(0,2)) have been studied by observing SO(A - X) emission in the beam apparatus. The nascent vibrational distribution of SO(A,v') was determined. A Surprisal analysis of the nascent vibrational distribution of SO(A) indicated that the precursor molecules dissociation could occur predominately from superexcited states (Rydberg-states). The formation rate constants of SO(A) have been determined for Ar(P-3(0,2))/SO2 and Ar(P-3(0,2))/SOCl2 reactions, They are: 4.55x10(-12)cm(3)-molcule(-1).s(-1) and 2.87x10(-12)cm(3).molecule(-1).s(-1), respectively. A comparison between the observed formation rate constants and known total quenching rate constants indicated that dissociative excitation processes are minor exit channels.
语种: 英语
WOS记录号: WOS:000207590000007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140655
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
2.CAS, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Sun Qi,Gu Yuezhu,Guo Jingzhong,et al. Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(1):31-37.
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