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Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition
Sun Qi1; Gu Yuezhu1; Guo Jingzhong1; Ying Yongjia1; Li Xuechu2; Shen Guanlin2
关键词Metastable Atom Dissociative Excitation Vibrational Distribution Reaction Channel
刊名ACTA PHYSICO-CHIMICA SINICA
1995
DOI10.3866/PKU.WHXB19950107
11期:1页:31-37
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要Dissociative excitation of SO2,SOCl2 through single collision with Ar(P-3(0,2)) have been studied by observing SO(A - X) emission in the beam apparatus. The nascent vibrational distribution of SO(A,v') was determined. A Surprisal analysis of the nascent vibrational distribution of SO(A) indicated that the precursor molecules dissociation could occur predominately from superexcited states (Rydberg-states). The formation rate constants of SO(A) have been determined for Ar(P-3(0,2))/SO2 and Ar(P-3(0,2))/SOCl2 reactions, They are: 4.55x10(-12)cm(3)-molcule(-1).s(-1) and 2.87x10(-12)cm(3).molecule(-1).s(-1), respectively. A comparison between the observed formation rate constants and known total quenching rate constants indicated that dissociative excitation processes are minor exit channels.
语种英语
WOS记录号WOS:000207590000007
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140655
专题中国科学院大连化学物理研究所
作者单位1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
2.CAS, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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GB/T 7714
Sun Qi,Gu Yuezhu,Guo Jingzhong,et al. Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(1):31-37.
APA Sun Qi,Gu Yuezhu,Guo Jingzhong,Ying Yongjia,Li Xuechu,&Shen Guanlin.(1995).Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition.ACTA PHYSICO-CHIMICA SINICA,11(1),31-37.
MLA Sun Qi,et al."Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition".ACTA PHYSICO-CHIMICA SINICA 11.1(1995):31-37.
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