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Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Wang, Xiao; Du, Juanjuan; Liu, Han; Du, Da-Ming; Xu, Jiaxi
刊名HETEROATOM CHEMISTRY
2007
DOI10.1002/hc.20370
18期:7页:740-746
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HIGH ENANTIOMERIC EXCESS ; PROCHIRAL KETONES ; CHIRAL OXAZABOROLIDINE ; CARBONYL-COMPOUNDS ; AROMATIC KETONES ; EFFICIENT SYNTHESIS ; SECONDARY ALCOHOLS ; PRACTICAL METHOD ; AMINO-ALCOHOLS ; REDUCING AGENT
英文摘要The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane as catalysts. The results indicate that the enantioselective order of different borane sources is borane-dimethyl sulfide < borane-N,N-diethylaniline < borane-THF for the asymmetric reduction of a ketone under the same conditions. (c) 2007 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000251367100005
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140662
专题中国科学院大连化学物理研究所
作者单位Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China
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GB/T 7714
Wang, Xiao,Du, Juanjuan,Liu, Han,et al. Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones[J]. HETEROATOM CHEMISTRY,2007,18(7):740-746.
APA Wang, Xiao,Du, Juanjuan,Liu, Han,Du, Da-Ming,&Xu, Jiaxi.(2007).Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones.HETEROATOM CHEMISTRY,18(7),740-746.
MLA Wang, Xiao,et al."Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones".HETEROATOM CHEMISTRY 18.7(2007):740-746.
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