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Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids
Shen Jianghan1,2; Wang Hua1; Sun Ying1,2; Liu Hongchao1,2; Liu Zhongmin1
关键词Ionic Liquid Bronsted Acid Iso-butanal Tert-butyl Alcohol Prins Condensation 2 5-dimethyl-2 4-hexadiene
刊名CHINESE JOURNAL OF CATALYSIS
2007-11-01
28期:11页:1009-1012
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]PRINS CONDENSATION ; ISOBUTYL ALDEHYDE ; ESTERIFICATION ; GREEN ; 2,5-DIMETHYL-2,4-HEXADIENE ; EFFICIENT ; SYSTEM
英文摘要Catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by Prins condensation of iso-butanal and tert-butyl alcohol was investigated using Bronsted acidic ionic liquids as both catalyst and solvent. It was found that all the ionic liquids were active for Prins condensation. After reaction, the upper organic phase could be easily separated from the ionic liquid by decantation. The ionic liquids could be reused in the next run by heat treatment under vacuum. Manipulating the structure of ionic liquids with respect to the organic cation or the organic/inorganic anion had great effects on the catalytic performance of the ionic liquids.
语种英语
WOS记录号WOS:000251594300016
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140666
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Grad Univ Beijing, Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Shen Jianghan,Wang Hua,Sun Ying,et al. Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(11):1009-1012.
APA Shen Jianghan,Wang Hua,Sun Ying,Liu Hongchao,&Liu Zhongmin.(2007).Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids.CHINESE JOURNAL OF CATALYSIS,28(11),1009-1012.
MLA Shen Jianghan,et al."Condensation of iso-butanal and tert-butyl alcohol catalyzed by bronsted acidic ionic liquids".CHINESE JOURNAL OF CATALYSIS 28.11(2007):1009-1012.
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