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Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy
Huang, Jiangou; Lin, Jung Lee; Tzeng, Wen Bih
关键词Cresol Rotamer Cation Spectra Multiphoton Ionization Threshold Ionization
刊名SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
2007-07-01
DOI10.1016/j.saa.2006.09.018
67期:3-4页:989-994
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Spectroscopy
研究领域[WOS]Spectroscopy
关键词[WOS]ROTATIONAL ISOMERS ; ELECTRONIC-SPECTRA ; VIBRATIONAL LEVELS ; SUPERSONIC JET ; ENERGY ; S-1 ; FLUOROANILINE ; POTENTIALS ; EXCITATION ; COMPLEXES
英文摘要We have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. The adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. Frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. This indicates that different orientation of the OH group with respect to the CH3 group slightly influences these ring vibrations. (C) 2006 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000247452400064
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140691
专题中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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GB/T 7714
Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):989-994.
APA Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,67(3-4),989-994.
MLA Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 67.3-4(2007):989-994.
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