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Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy
Huang, Jiangou; Lin, Jung Lee; Tzeng, Wen Bih
KeywordCresol Rotamer Cation Spectra Multiphoton Ionization Threshold Ionization
Source PublicationSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
2007-07-01
DOI10.1016/j.saa.2006.09.018
Volume67Issue:3-4Pages:989-994
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
WOS SubjectSpectroscopy
WOS Research AreaSpectroscopy
WOS KeywordROTATIONAL ISOMERS ; ELECTRONIC-SPECTRA ; VIBRATIONAL LEVELS ; SUPERSONIC JET ; ENERGY ; S-1 ; FLUOROANILINE ; POTENTIALS ; EXCITATION ; COMPLEXES
AbstractWe have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. The adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. Frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. This indicates that different orientation of the OH group with respect to the CH3 group slightly influences these ring vibrations. (C) 2006 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000247452400064
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140691
Collection中国科学院大连化学物理研究所
Affiliation1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):989-994.
APA Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,67(3-4),989-994.
MLA Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 67.3-4(2007):989-994.
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