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题名: Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy
作者: Huang, Jiangou;  Lin, Jung Lee;  Tzeng, Wen Bih
关键词: cresol ;  rotamer ;  cation spectra ;  multiphoton ionization ;  threshold ionization
刊名: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
发表日期: 2007-07-01
DOI: 10.1016/j.saa.2006.09.018
卷: 67, 期:3-4, 页:989-994
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Spectroscopy
研究领域[WOS]: Spectroscopy
英文摘要: We have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. The adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. Frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. This indicates that different orientation of the OH group with respect to the CH3 group slightly influences these ring vibrations. (C) 2006 Elsevier B.V. All rights reserved.
关键词[WOS]: ROTATIONAL ISOMERS ;  ELECTRONIC-SPECTRA ;  VIBRATIONAL LEVELS ;  SUPERSONIC JET ;  ENERGY ;  S-1 ;  FLUOROANILINE ;  POTENTIALS ;  EXCITATION ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000247452400064
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140691
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):989-994.
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