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题名: Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex
作者: Shi, Ji-cheng;  Lei, Ni;  Tong, Qingsong;  Peng, Yiru;  Wei, Junfa;  Jia, Li
关键词: nitrogen heterocycles ;  carbenes ;  rhodium ;  carbohydrates ;  chirality
刊名: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2007-05-01
DOI: 10.1002/ejic.200700027
期: 15, 页:2221-2224
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: A chiral imidazolinium salt with two bulky carbohydrate subunits, N,N'-1,3-bis(methyl 4,6-0-benzylidene-3-deoxy-alpha-D-altropyrano-3-yl)imidazolinium chloride (4), was synthesized in high yield. Deprotonation of 4 with sodium tert-butoxide in the presence of [RhCl(COD)](2) produced NHC-coordinated rhodium complex 5 along with water adduct 6 to a lesser extent depending on the moisture content of the reaction mixture. These compounds were fully characterized by IR, MS, and (1)H and (13)C{(1)H) NMR spectroscopy. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
关键词[WOS]: N-HETEROCYCLIC CARBENES ;  OLEFIN METATHESIS CATALYSTS ;  PHOSPHINE-LIGANDS ;  SPECTROSCOPIC PROPERTIES ;  PALLADIUM(II) COMPLEXES ;  PLATINUM(II) COMPLEXES ;  HOMOGENEOUS CATALYSIS ;  GOLD(I) COMPLEXES ;  METAL-COMPLEXES ;  ARYL BROMIDES
语种: 英语
WOS记录号: WOS:000246856900014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140708
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
2.Shaanxi Normal Univ, Dept Chem, Xian 710062, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Shi, Ji-cheng,Lei, Ni,Tong, Qingsong,et al. Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2007(15):2221-2224.
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