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A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials
Li, Qingwei; Chen, Fang; Zhao, Weili; Xu, Mingxiu; Fang, Benjie; Zhang, Yuelong; Duo, Liping; Jin, Yuqi; Sang, Fengting
关键词Singlet Oxygen Peroxides Emission Spectroscopy Reactions Chlorine
刊名BULLETIN OF THE KOREAN CHEMICAL SOCIETY
2007-10-20
28期:10页:1656-1660
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]EFFICIENCY FACTORS ; SOLVENT SHIFT ; GENERATION ; OXIDATION ; LIFETIME
英文摘要Using solid inorganic peroxides (including Li2O2, Na2O2, SrO2 and BaO2) as starting materials, three reaction paths for singlet oxygen (O-1(2)) production were developed and studied. Their O-1(2) emission spectra in the near-IR region and visible region from these reaction paths were simultaneously recorded by a near-IR sensitive Optical Multichannel Analyzer and a visible sensitive Optical Spectrum Analyzer, respectively. The comparison of their 102 emission spectra indicated that: (1) in term of the efficiency for 102 production, the gas-liquid-solid ;reaction path (in which Cl-2 or HCl and H2O reacted with the solid inorganic peroxides suspension in CCl4) was prior to the gas-solid reaction path (in which Cl-2 or HCl reacted with the solid inorganic peroxides suspension in CCl4), but was inferior to the gas-liquid reaction path (in which Cl-2 or HCl reacted with the solid inorganic peroxides solution in H2O or D2O); (2) the alkali metal peroxides (such as Li2O2 and Na2O2) was prior to the alkaline earth metal peroxides (such as SrO2 and BaO2) as the solid reactants, and Cl-2 was favorable than HCl as the gas reactant in efficiency for O-1(2) production in these reaction paths.
语种英语
WOS记录号WOS:000251301600008
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140722
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Lab Chem Lasers, Dalian 116023, Peoples R China
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GB/T 7714
Li, Qingwei,Chen, Fang,Zhao, Weili,et al. A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY,2007,28(10):1656-1660.
APA Li, Qingwei.,Chen, Fang.,Zhao, Weili.,Xu, Mingxiu.,Fang, Benjie.,...&Sang, Fengting.(2007).A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials.BULLETIN OF THE KOREAN CHEMICAL SOCIETY,28(10),1656-1660.
MLA Li, Qingwei,et al."A spectroscopic study on singlet oxygen production from different reaction paths using solid inorganic peroxides as starting materials".BULLETIN OF THE KOREAN CHEMICAL SOCIETY 28.10(2007):1656-1660.
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