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MgAPSO-34 molecular sieves with various Mg stoichiometries: Synthesis, characterization and catalytic behavior in the direct transformation of chloromethane into light olefins
Zhang, Dazhi2; Wei, Yingxu2; Xu, Lei2; Chang, Fuxiang2; Liu, Ziyu2; Meng, Shuanghe2; Su, Bao-Lian1,2; Liu, Zhongmin2
关键词Mgapso-34 Sapo-34 Mg Incorporation Chloromethane Conversion Light Olefins
刊名MICROPOROUS AND MESOPOROUS MATERIALS
2008-12-01
DOI10.1016/j.micromeso.2008.06.001
116期:1-3页:684-692
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]TRANSITION-METAL IONS ; HIGHER HYDROCARBONS ; INFRARED-SPECTROSCOPY ; INCORPORATED SAPO-34 ; CHABAZITE STRUCTURE ; CONVERSION ; METHANOL ; ZEOLITE ; ALUMINUM ; ACIDITY
英文摘要A series of MgAPSO-34s with various Mg stoichiometries were synthesized, characterized by multiple techniques such as, powder XRD, solid state MAS NMR, DR UV-vis spectrometry, NH(3)-TPD and FTIR and used as catalysts in the direct conversion of chloromethane into light olefins. XRD results revealed that the unit cell parameters of the CHA structure increased with Mg incorporation. The appearance of some new peaks in the (31)P MAS NMR spectra of MgAPSO-34 indicated new P co-ordination states as a result of the substitution of Al by Mg. Mg incorporation also modified the Si co-ordination states. A DR UV-vis spectroscopic study evidenced that, in comparison with an MgO crystal, the Mg species in the MgAPSO-34s were quite different. These changes in crystal structure and the chemical environment of framework elements created by Mg substitution modified the acidity and catalytic properties. The acidity of SAPO-34 and MgAPSO-34 determined with NH(3)-TPD and FTIR techniques showed that the amount of acid sites, especially those of strong acidity, is reduced with the increase of Mg incorporation. Direct chloromethane transformation was carried out over SAPO-34 and MgAPSO-34. All the samples were very active and selective catalysts for light olefin production from chloromethane. Compared with SAPO-34, MgAPSO-34 showed an enhanced conversion, longer catalyst life and improved light olefin selectivity. (C) 2008 Elsevier Inc. All rights reserved.
语种英语
WOS记录号WOS:000261133600096
引用统计
被引频次:55[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140755
专题中国科学院大连化学物理研究所
作者单位1.Univ Namur FUNDP, Lab Inorgan Mat Chem, B-5000 Namur, Belgium
2.Chinese Acad Sci, Dalian Inst Chem Phys, Appl Catalysis Lab, Dalian 116023, Peoples R China
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Zhang, Dazhi,Wei, Yingxu,Xu, Lei,et al. MgAPSO-34 molecular sieves with various Mg stoichiometries: Synthesis, characterization and catalytic behavior in the direct transformation of chloromethane into light olefins[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2008,116(1-3):684-692.
APA Zhang, Dazhi.,Wei, Yingxu.,Xu, Lei.,Chang, Fuxiang.,Liu, Ziyu.,...&Liu, Zhongmin.(2008).MgAPSO-34 molecular sieves with various Mg stoichiometries: Synthesis, characterization and catalytic behavior in the direct transformation of chloromethane into light olefins.MICROPOROUS AND MESOPOROUS MATERIALS,116(1-3),684-692.
MLA Zhang, Dazhi,et al."MgAPSO-34 molecular sieves with various Mg stoichiometries: Synthesis, characterization and catalytic behavior in the direct transformation of chloromethane into light olefins".MICROPOROUS AND MESOPOROUS MATERIALS 116.1-3(2008):684-692.
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